Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes
Weber L, Pumpenmeier L, Stammler H-G, Neumann B (2004)
Journal of the Chemical Society. Dalton Transactions (4): 659-667.
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Abstract / Bemerkung
Reaction of one equivalent of the complexes [FeCp*(CO)(2)PnCl(2)] (Pn=P, As, Sb) with tetramethylcyclopentadienyl-lithium afforded compounds [FeCp*(CO)(2){Pn(Cl)(C5Me4H)}]. Dehydrochlorination by means of tert-butyllithium led to decomposition. Only in the case of the phosphorus compound was evidence for the initial formation of a phosphaalkene given by P-31 NMR spectroscopy. Similarly treatment of equimolar amounts of [FeCp*(CO)(2)PnCl(2)] with 2,7-di-tert-butyl-9-H-fluorenyllithium or 2,7-di-tert-butyl-9-trimethylsilylfluorenyllithium yielded the asymmetrically substituted ferriopnicogenanes [FeCp*(CO)(2){Pn(Cl)-9-R-Fl*}] (Pn=P, As, Sb; R=H, Me3Si; Fl*=2,7-di-tert-butylfluorenylidene). Dehydrohalogenation of [FeCp*(CO)(2){Pn(Cl)-9-H-Fl*}] with lithium diisopropylamide resulted in the formation of the anticipated phosphaalkene [FeCp*(CO)(2){P=Fl*}], whereas in the case of the arsenic and antimony derivatives the novel ferriopnicogenanes [FeCp*(CO)(2){Pn(9-H-Fl*)(2)}] (Pn=As, Sb) were obtained as products. The new compounds were characterized by elemental analyses and spectra (IR, H-1, C-13, Si-29, P-31 NMR). The molecular structures of [FeCp*(CO)(2){Pn(Cl)(C5Me4H]}] (Pn=As, Sb), [FeCp*(CO)(2){As(Cl)-(9-Me3Si-Fl*)}] and [FeCp*(CO)(2){Sb(9-H-Fl*}(2)] were elucidated by single X-ray diffraction analyses.
Erscheinungsjahr
2004
Zeitschriftentitel
Journal of the Chemical Society. Dalton Transactions
Ausgabe
4
Seite(n)
659-667
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1608798
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Weber L, Pumpenmeier L, Stammler H-G, Neumann B. Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions. 2004;(4):659-667.
Weber, L., Pumpenmeier, L., Stammler, H. - G., & Neumann, B. (2004). Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions(4), 659-667. https://doi.org/10.1039/b315221a
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. 2004. “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”. Journal of the Chemical Society. Dalton Transactions, no. 4: 659-667.
Weber, L., Pumpenmeier, L., Stammler, H. - G., and Neumann, B. (2004). Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions, 659-667.
Weber, L., et al., 2004. Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions, (4), p 659-667.
L. Weber, et al., “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”, Journal of the Chemical Society. Dalton Transactions, 2004, pp. 659-667.
Weber, L., Pumpenmeier, L., Stammler, H.-G., Neumann, B.: Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions. 659-667 (2004).
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”. Journal of the Chemical Society. Dalton Transactions 4 (2004): 659-667.
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33 References
Daten bereitgestellt von Europe PubMed Central.
Weber, Eur. J. Inorg. Chem. (), 2000
Weber, Angew. Chem. 108(), 1996
Weber, Angew. Chem., Int. Ed. Engl. 35(), 1996
Märkl, Tetrahedron Lett. 30(), 1989
van, Chem. Ber. 117(), 1984
Toyota, Chem. Lett. 32(), 2003
Nucleophilic Addition of CH, NH, and OH Bonds to the Phosphadiazonium Cation and Interpretation of (31)P Chemical Shifts at Dicoordinate Phosphorus Centers.
Burford N, Cameron TS, Clyburne JA, Eichele K, Robertson KN, Sereda S, Wasylishen RE, Whitla WA., Inorg Chem 35(19), 1996
PMID: 11666731
Burford N, Cameron TS, Clyburne JA, Eichele K, Robertson KN, Sereda S, Wasylishen RE, Whitla WA., Inorg Chem 35(19), 1996
PMID: 11666731
Decken, Inorg. Chem. 36(), 1997
Weber, Z. Anorg. Allg. Chem. 549(), 1987
Weber, Z. Anorg. Allg. Chem. 626(), 2000
Gröer, J. Chem. Soc., Dalton Trans. (), 2000
Malisch, Z. Naturforsch., B 30(), 1975
Panster, Chem. Ber. 109(), 1976
Becker, Z. Anorg. Allg. Chem. 492(), 1982
Niecke, Chem. Ber. 126(), 1993
Weber, Z. Anorg. Allg. Chem. 626(), 2000
Weber, Chem. Ber. 129(), 1996
Winter, J. Organomet. Chem. 234(), 1982
Ehleiter, Z. Anorg. Allg. Chem. 622(), 1996
Weber, J. Chem. Soc., Dalton Trans. (), 2000
Bartlett, Organometallics 11(), 1992
Appel, 1990
Dillon, 1998
Weber, Chem. Ber. 129(), 1996
Durkin, J. Chem. Soc., Dalton Trans. (), 1996
Jones, Coord. Chem. Rev. 215(), 2001
Jones, J. Chem. Soc., Dalton Trans. (), 1999
Hitchcock, Angew. Chem. 107(), 1995
Hitchcock, Angew. Chem., Int. Ed. Engl. 34(), 1995
Weber, Chem. Ber. 124(), 1991
Catheline, J. Organomet. Chem. 226(), 1982
Schmitt, Chem.-Zeit. 100(), 1976
Kaplan, J. Am. Chem. Soc. 99(), 1977
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