Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes

Weber L, Pumpenmeier L, Stammler H-G, Neumann B (2004)
Journal of the Chemical Society. Dalton Transactions (4): 659-667.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Weber, LotharUniBi; Pumpenmeier, Lars; Stammler, Hans-GeorgUniBi; Neumann, BeateUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie II
Abstract / Bemerkung
Reaction of one equivalent of the complexes [FeCp*(CO)(2)PnCl(2)] (Pn=P, As, Sb) with tetramethylcyclopentadienyl-lithium afforded compounds [FeCp*(CO)(2){Pn(Cl)(C5Me4H)}]. Dehydrochlorination by means of tert-butyllithium led to decomposition. Only in the case of the phosphorus compound was evidence for the initial formation of a phosphaalkene given by P-31 NMR spectroscopy. Similarly treatment of equimolar amounts of [FeCp*(CO)(2)PnCl(2)] with 2,7-di-tert-butyl-9-H-fluorenyllithium or 2,7-di-tert-butyl-9-trimethylsilylfluorenyllithium yielded the asymmetrically substituted ferriopnicogenanes [FeCp*(CO)(2){Pn(Cl)-9-R-Fl*}] (Pn=P, As, Sb; R=H, Me3Si; Fl*=2,7-di-tert-butylfluorenylidene). Dehydrohalogenation of [FeCp*(CO)(2){Pn(Cl)-9-H-Fl*}] with lithium diisopropylamide resulted in the formation of the anticipated phosphaalkene [FeCp*(CO)(2){P=Fl*}], whereas in the case of the arsenic and antimony derivatives the novel ferriopnicogenanes [FeCp*(CO)(2){Pn(9-H-Fl*)(2)}] (Pn=As, Sb) were obtained as products. The new compounds were characterized by elemental analyses and spectra (IR, H-1, C-13, Si-29, P-31 NMR). The molecular structures of [FeCp*(CO)(2){Pn(Cl)(C5Me4H]}] (Pn=As, Sb), [FeCp*(CO)(2){As(Cl)-(9-Me3Si-Fl*)}] and [FeCp*(CO)(2){Sb(9-H-Fl*}(2)] were elucidated by single X-ray diffraction analyses.
Erscheinungsjahr
2004
Zeitschriftentitel
Journal of the Chemical Society. Dalton Transactions
Ausgabe
4
Seite(n)
659-667
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1608798

Zitieren

Weber L, Pumpenmeier L, Stammler H-G, Neumann B. Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions. 2004;(4):659-667.
Weber, L., Pumpenmeier, L., Stammler, H. - G., & Neumann, B. (2004). Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions(4), 659-667. https://doi.org/10.1039/b315221a
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. 2004. “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”. Journal of the Chemical Society. Dalton Transactions, no. 4: 659-667.
Weber, L., Pumpenmeier, L., Stammler, H. - G., and Neumann, B. (2004). Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions, 659-667.
Weber, L., et al., 2004. Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions, (4), p 659-667.
L. Weber, et al., “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”, Journal of the Chemical Society. Dalton Transactions, 2004, pp. 659-667.
Weber, L., Pumpenmeier, L., Stammler, H.-G., Neumann, B.: Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes. Journal of the Chemical Society. Dalton Transactions. 659-667 (2004).
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. “Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2 [η-C5Me5)FePn(Cl)R] (Pn=P, As, Sb); (R= tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes and -stilbaalkenes”. Journal of the Chemical Society. Dalton Transactions 4 (2004): 659-667.

33 References

Daten bereitgestellt von Europe PubMed Central.


Weber, Eur. J. Inorg. Chem. (), 2000

Weber, Angew. Chem. 108(), 1996

Weber, Angew. Chem., Int. Ed. Engl. 35(), 1996

Märkl, Tetrahedron Lett. 30(), 1989

van, Chem. Ber. 117(), 1984

Toyota, Chem. Lett. 32(), 2003
Nucleophilic Addition of CH, NH, and OH Bonds to the Phosphadiazonium Cation and Interpretation of (31)P Chemical Shifts at Dicoordinate Phosphorus Centers.
Burford N, Cameron TS, Clyburne JA, Eichele K, Robertson KN, Sereda S, Wasylishen RE, Whitla WA., Inorg Chem 35(19), 1996
PMID: 11666731

Decken, Inorg. Chem. 36(), 1997

Weber, Z. Anorg. Allg. Chem. 549(), 1987

Weber, Z. Anorg. Allg. Chem. 626(), 2000

Gröer, J. Chem. Soc., Dalton Trans. (), 2000

Malisch, Z. Naturforsch., B 30(), 1975

Panster, Chem. Ber. 109(), 1976

Becker, Z. Anorg. Allg. Chem. 492(), 1982

Niecke, Chem. Ber. 126(), 1993

Weber, Z. Anorg. Allg. Chem. 626(), 2000

Weber, Chem. Ber. 129(), 1996

Winter, J. Organomet. Chem. 234(), 1982

Ehleiter, Z. Anorg. Allg. Chem. 622(), 1996

Weber, J. Chem. Soc., Dalton Trans. (), 2000

Bartlett, Organometallics 11(), 1992

Appel, 1990

Dillon, 1998

Weber, Chem. Ber. 129(), 1996

Durkin, J. Chem. Soc., Dalton Trans. (), 1996

Jones, Coord. Chem. Rev. 215(), 2001

Jones, J. Chem. Soc., Dalton Trans. (), 1999

Hitchcock, Angew. Chem. 107(), 1995

Hitchcock, Angew. Chem., Int. Ed. Engl. 34(), 1995

Weber, Chem. Ber. 124(), 1991

Catheline, J. Organomet. Chem. 226(), 1982

Schmitt, Chem.-Zeit. 100(), 1976

Kaplan, J. Am. Chem. Soc. 99(), 1977
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 15252531
PubMed | Europe PMC

Suchen in

Google Scholar