Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers

Bunte JO, Rinne S, Mattay J (2004)
SYNTHESIS-STUTTGART (4): 619-633.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Bunte, JO; Rinne, S; Mattay, JochenUniBi
Abstract / Bemerkung
Photoinduced electron transfer was used to activate silyl enol ethers. The generated radical cations of specifically designed precursors undergo ring closure reactions to yield novel steroid compounds. These domino reactions proceed with high stereo-selectivity. The synthesis of the complex silyl enol ethers, the stereo-selective domino cyclization process and the assignment of stereochemistry of the novel steroid compounds is presented.
Stichworte
domino reactions; stereoselectivity; steroids; electron transfer; cyclizations
Erscheinungsjahr
2004
Zeitschriftentitel
SYNTHESIS-STUTTGART
Ausgabe
4
Seite(n)
619-633
ISSN
0039-7881
eISSN
1437-210X
Page URI
https://pub.uni-bielefeld.de/record/1608400

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Bunte JO, Rinne S, Mattay J. Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers. SYNTHESIS-STUTTGART. 2004;(4):619-633.
Bunte, J. O., Rinne, S., & Mattay, J. (2004). Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers. SYNTHESIS-STUTTGART(4), 619-633. doi:10.1055/s-2004-815956
Bunte, J. O., Rinne, S., and Mattay, J. (2004). Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers. SYNTHESIS-STUTTGART, 619-633.
Bunte, J.O., Rinne, S., & Mattay, J., 2004. Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers. SYNTHESIS-STUTTGART, (4), p 619-633.
J.O. Bunte, S. Rinne, and J. Mattay, “Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers”, SYNTHESIS-STUTTGART, 2004, pp. 619-633.
Bunte, J.O., Rinne, S., Mattay, J.: Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers. SYNTHESIS-STUTTGART. 619-633 (2004).
Bunte, JO, Rinne, S, and Mattay, Jochen. “Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers”. SYNTHESIS-STUTTGART 4 (2004): 619-633.

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