The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study

Schoeller W, Eisner D (2004)
INORGANIC CHEMISTRY 43(8): 2585-2589.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Schoeller, WolfgangUniBi; Eisner, D
Einrichtung
Fakultät für Chemie > Theoretische Chemie
Abstract / Bemerkung
The 1,4-diphosphabuta-1,3-diene (DPB) ligand as a tool for stabilizing anionic group 13 (B, Al, Ga) and neutral group 14 (C, Si, Ge) cyclic Arduengo-type carbenes is studied by quantum chemical calculations at density functional level. Accordingly, for the former group this ligand is better suited than the corresponding 1,4-diazabuta-1,3-diene (DAB) ligand. It results in larger electron affinities for the corresponding doublet states. For the latter group the DPB ligand yields essentially smaller singlet-triplet separations than the DAB ligand. An exception is the anionic boron compound with relative low singlet stability for both the DAB and DPB ligands.
Erscheinungsjahr
2004
Zeitschriftentitel
INORGANIC CHEMISTRY
Band
43
Ausgabe
8
Seite(n)
2585-2589
ISSN
0020-1669
eISSN
1520-510X
Page URI
https://pub.uni-bielefeld.de/record/1608045

Zitieren

Schoeller W, Eisner D. The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study. INORGANIC CHEMISTRY. 2004;43(8):2585-2589.
Schoeller, W., & Eisner, D. (2004). The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study. INORGANIC CHEMISTRY, 43(8), 2585-2589. https://doi.org/10.1021/ic030234u
Schoeller, Wolfgang, and Eisner, D. 2004. “The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study”. INORGANIC CHEMISTRY 43 (8): 2585-2589.
Schoeller, W., and Eisner, D. (2004). The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study. INORGANIC CHEMISTRY 43, 2585-2589.
Schoeller, W., & Eisner, D., 2004. The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study. INORGANIC CHEMISTRY, 43(8), p 2585-2589.
W. Schoeller and D. Eisner, “The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study”, INORGANIC CHEMISTRY, vol. 43, 2004, pp. 2585-2589.
Schoeller, W., Eisner, D.: The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study. INORGANIC CHEMISTRY. 43, 2585-2589 (2004).
Schoeller, Wolfgang, and Eisner, D. “The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: A density functional study”. INORGANIC CHEMISTRY 43.8 (2004): 2585-2589.

14 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons.
Rottschäfer D, Ho NKT, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS., Angew Chem Int Ed Engl 57(20), 2018
PMID: 29668119
Chemical behaviour of a prototype boryl(phosphino)carbene.
Lavigne F, Maerten E, Alcaraz G, Saffon-Merceron N, Baceiredo A., Chemistry 20(1), 2014
PMID: 24285643
Ruthenium(II) complexes of N-heterocyclic carbenes derived from imidazolium-linked cyclophanes.
Caramori GF, Garcia LC, Andrada DM, Frenking G., Dalton Trans 43(39), 2014
PMID: 25144142
Theoretical design of the biradical character in 1,3-diphosphacyclobutanediyl and homologous structures.
Schoeller WW, Niecke E., Phys Chem Chem Phys 14(6), 2012
PMID: 22228139
An unexpected dependence on the SnII base; reactions of Sn(NR2)2 with aromatic dithiols.
Melen RL, McPartlin M, Wright DS., Dalton Trans 40(8), 2011
PMID: 21258731
Aromatic ylide-stabilized carbocyclic silylene.
Asay M, Inoue S, Driess M., Angew Chem Int Ed Engl 50(41), 2011
PMID: 21882326
Theoretical investigations of the reactivities of lattice-framework carbene analogues of the group 14 elements.
Hsiao J, Su MD., Dalton Trans 39(39), 2010
PMID: 20652200
Stable cyclic carbenes and related species beyond diaminocarbenes.
Melaimi M, Soleilhavoup M, Bertrand G., Angew Chem Int Ed Engl 49(47), 2010
PMID: 20836099
Heterocyclic carbenes: synthesis and coordination chemistry.
Hahn FE, Jahnke MC., Angew Chem Int Ed Engl 47(17), 2008
PMID: 18398856
Bis-phosphorus stabilised carbene complexes.
Cantat T, Mézailles N, Auffrant A, Le Floch P., Dalton Trans (15), 2008
PMID: 18382770
The 6pi, phosphide-stabilised stannylene dianion [C6H4P2Sn]2-; the first member of a new class of Arduengo-type carbene analogues.
Eisler DJ, Less RJ, Naseri V, Rawson JM, Wright DS., Dalton Trans (18), 2008
PMID: 18461190
Heterocyclic carbenes.
Hahn FE., Angew Chem Int Ed Engl 45(9), 2006
PMID: 16447297
P-Heterocyclic carbenes as potential ligands in the design of new metathesis catalysts. A computational study.
Jacobsen H., Dalton Trans (18), 2006
PMID: 16673036
A stable P-heterocyclic carbene.
Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G., Angew Chem Int Ed Engl 44(11), 2005
PMID: 15712311
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 15074977
PubMed | Europe PMC

Suchen in

Google Scholar