Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group

Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller W, Bourissou D, Bertrand G (2004)
INORGANIC CHEMISTRY 43(21): 6546-6548.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Dumitrescu, A; Rudzevich, VL; Romanenko, VD; Mari, A; Schoeller, WolfgangUniBi; Bourissou, D; Bertrand, G
Einrichtung
Fakultät für Chemie > Theoretische Chemie
Abstract / Bemerkung
Persistent phosphinyl radicals featuring the 2,6-bis(trifluoromethyl)-phenyl group were prepared and characterized. Their electronic structure was theoretically investigated, and their low-temperature dimerization into the corresponding diphosphines was found to be strongly inhibited when the sterically very demanding (tert-butyl)-(trimethylsilyl)amino substituent was used.
Erscheinungsjahr
2004
Zeitschriftentitel
INORGANIC CHEMISTRY
Band
43
Ausgabe
21
Seite(n)
6546-6548
ISSN
0020-1669
eISSN
1520-510X
Page URI
https://pub.uni-bielefeld.de/record/1606242

Zitieren

Dumitrescu A, Rudzevich VL, Romanenko VD, et al. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. INORGANIC CHEMISTRY. 2004;43(21):6546-6548.
Dumitrescu, A., Rudzevich, V. L., Romanenko, V. D., Mari, A., Schoeller, W., Bourissou, D., & Bertrand, G. (2004). Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. INORGANIC CHEMISTRY, 43(21), 6546-6548. https://doi.org/10.1021/ic049152b
Dumitrescu, A, Rudzevich, VL, Romanenko, VD, Mari, A, Schoeller, Wolfgang, Bourissou, D, and Bertrand, G. 2004. “Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group”. INORGANIC CHEMISTRY 43 (21): 6546-6548.
Dumitrescu, A., Rudzevich, V. L., Romanenko, V. D., Mari, A., Schoeller, W., Bourissou, D., and Bertrand, G. (2004). Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. INORGANIC CHEMISTRY 43, 6546-6548.
Dumitrescu, A., et al., 2004. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. INORGANIC CHEMISTRY, 43(21), p 6546-6548.
A. Dumitrescu, et al., “Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group”, INORGANIC CHEMISTRY, vol. 43, 2004, pp. 6546-6548.
Dumitrescu, A., Rudzevich, V.L., Romanenko, V.D., Mari, A., Schoeller, W., Bourissou, D., Bertrand, G.: Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. INORGANIC CHEMISTRY. 43, 6546-6548 (2004).
Dumitrescu, A, Rudzevich, VL, Romanenko, VD, Mari, A, Schoeller, Wolfgang, Bourissou, D, and Bertrand, G. “Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group”. INORGANIC CHEMISTRY 43.21 (2004): 6546-6548.

6 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

On the energetics of P-P bond dissociation of sterically strained tetraamino-diphosphanes.
Blum M, Puntigam O, Plebst S, Ehret F, Bender J, Nieger M, Gudat D., Dalton Trans 45(5), 2016
PMID: 26337501
Diphosphane 2,2'-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation.
Kirst C, Bode BE, Cordes DB, Nejman PS, Slawin AM, Karaghiosoff K, Woollins JD., Dalton Trans 45(15), 2016
PMID: 26988270
Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes.
Giffin NA, Hendsbee AD, Masuda JD., Dalton Trans 45(32), 2016
PMID: 27443569
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Witwicki M., Chemphyschem 16(9), 2015
PMID: 25873130
A stable dialkylphosphinyl radical.
Ishida S, Hirakawa F, Iwamoto T., J Am Chem Soc 133(33), 2011
PMID: 21776957
An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple.
Agarwal P, Piro NA, Meyer K, Müller P, Cummins CC., Angew Chem Int Ed Engl 46(17), 2007
PMID: 17351998
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