On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation
Müller A, Botar B, Das SK, Bögge H, Schmidtmann M, Merca A (2004)
Polyhedron 23(15): 2381-2385.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Müller, AchimUniBi 
;
Botar, Bogdan;
Das, Samar K.;
Bögge, HartmutUniBi;
Schmidtmann, Marc;
Merca, AliceUniBi
;
Botar, Bogdan;
Das, Samar K.;
Bögge, HartmutUniBi;
Schmidtmann, Marc;
Merca, AliceUniBiEinrichtung
Abstract / Bemerkung
The deep-blue compound Na-48[HxMo368O1032(H2O)(240)(SO4)(48)] (.) ca. 1000H(2)O equivalent to Na-48 1a (.) ca. 1000H(2)O (1) exhibiting an unusual nanosized hedgehog-type cluster anion, could now be obtained in good yield - allowing now several materials science studies - in the presence of a high concentration of an electrolyte destroying the hydration shell, in only two days. 1 was characterized by elemental analysis (including redox titrations to determine the (formal) number of Mo-nu centers), thermogravimetry and spectroscopic methods (IR, resonance Raman, Vis/NIR). Information about unusual aspects of the formation is reported together with additional spectroscopic details as well Lis a new crystal structure determination of the very complex system while confirming the earlier one. (C) 2004 Elsevier Ltd. All rights reserved.
Stichworte
polyoxomolybdates;
nanochemistry;
clusters;
complexity
Erscheinungsjahr
2004
Zeitschriftentitel
Polyhedron
Band
23
Ausgabe
15
Seite(n)
2381-2385
ISSN
0277-5387
Page URI
https://pub.uni-bielefeld.de/record/1606220
Zitieren
Müller A, Botar B, Das SK, Bögge H, Schmidtmann M, Merca A. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron. 2004;23(15):2381-2385.
Müller, A., Botar, B., Das, S. K., Bögge, H., Schmidtmann, M., & Merca, A. (2004). On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron, 23(15), 2381-2385. https://doi.org/10.1016/j.poly.2004.07.018
Müller, Achim, Botar, Bogdan, Das, Samar K., Bögge, Hartmut, Schmidtmann, Marc, and Merca, Alice. 2004. “On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation”. Polyhedron 23 (15): 2381-2385.
Müller, A., Botar, B., Das, S. K., Bögge, H., Schmidtmann, M., and Merca, A. (2004). On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron 23, 2381-2385.
Müller, A., et al., 2004. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron, 23(15), p 2381-2385.
A. Müller, et al., “On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation”, Polyhedron, vol. 23, 2004, pp. 2381-2385.
Müller, A., Botar, B., Das, S.K., Bögge, H., Schmidtmann, M., Merca, A.: On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation. Polyhedron. 23, 2381-2385 (2004).
Müller, Achim, Botar, Bogdan, Das, Samar K., Bögge, Hartmut, Schmidtmann, Marc, and Merca, Alice. “On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation”. Polyhedron 23.15 (2004): 2381-2385.
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