A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide

Jaworski JS, Kuck D (2004)
POLISH JOURNAL OF CHEMISTRY 78(9): 1597-1604.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
The mechanism of electroreduction of 9-triptindanone (1), 9,10-triptindanedione (2), and 9,10,11-triptindanetrione (3) was studied by use of the cyclic voltammetric method. All carbonyl groups were reduced giving one, two, and three one-electron cathodic peaks for 1, 2, and 3, respectively and the corresponding oxidation peaks. The first electron transfer is reversible and the radical anions formed are stable. Additional small peaks for 2 and 3 were discussed in terms of an adsorption of reactants and intermediates and their reactions with the participation of supporting electrolyte cations as well as the residual water.
Stichworte
propellanes; electroreduction; 3-diketones; 1; radical anions; triptindanones
Erscheinungsjahr
2004
Zeitschriftentitel
POLISH JOURNAL OF CHEMISTRY
Band
78
Ausgabe
9
Seite(n)
1597-1604
ISSN
0137-5083
Page URI
https://pub.uni-bielefeld.de/record/1606118

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Jaworski JS, Kuck D. A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide. POLISH JOURNAL OF CHEMISTRY. 2004;78(9):1597-1604.
Jaworski, J. S., & Kuck, D. (2004). A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide. POLISH JOURNAL OF CHEMISTRY, 78(9), 1597-1604.
Jaworski, J. S., and Kuck, D. (2004). A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide. POLISH JOURNAL OF CHEMISTRY 78, 1597-1604.
Jaworski, J.S., & Kuck, D., 2004. A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide. POLISH JOURNAL OF CHEMISTRY, 78(9), p 1597-1604.
J.S. Jaworski and D. Kuck, “A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide”, POLISH JOURNAL OF CHEMISTRY, vol. 78, 2004, pp. 1597-1604.
Jaworski, J.S., Kuck, D.: A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide. POLISH JOURNAL OF CHEMISTRY. 78, 1597-1604 (2004).
Jaworski, J. S., and Kuck, Dietmar. “A voltammetric study of the reduction of triptindanones in N,N-dimethylformamide”. POLISH JOURNAL OF CHEMISTRY 78.9 (2004): 1597-1604.