The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine)

Madalan AM, Melnic E, Kravtsov VC, Simonov YA, Schmidtmann M, Müller A, Andruh M (2004)
REVISTA DE CHIMIE 55(9): 678-682.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Madalan, A. M.; Melnic, E; Kravtsov, V. C.; Simonov, Y. A.; Schmidtmann, Marc; Müller, AchimUniBi ; Andruh, Marius
Abstract / Bemerkung
Two new mononuclear complexes belonging to the series [Cu(sal)(AA)(ClO4)] (sal = salicylaldehydate, AA = aromatic diamines) have been obtained and crystallographically characterized. In the two compounds, [Cu(sal)(Me-2-bipy)(ClO4)] and [Cu(sal)(bipym)(ClO4)] (Me-2-bipy = 4,4'-dimethyl-2,2 bipyridine; bipym = 2,2'-bipyrimidine), the copper(II) ions exhibit a square pyramidal geometry with the chelatic ligands forming the basal plane and the perclorate anion coordinated in the apical position. The spectral properties of the two compounds were investigated in UV, visible and IR domains.
Stichworte
copper(II) complexes; UV spectra; pi-pi stacking; crystal structure
Erscheinungsjahr
2004
Zeitschriftentitel
REVISTA DE CHIMIE
Band
55
Ausgabe
9
Seite(n)
678-682
ISSN
0034-7752
Page URI
https://pub.uni-bielefeld.de/record/1606110

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Madalan AM, Melnic E, Kravtsov VC, et al. The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine). REVISTA DE CHIMIE. 2004;55(9):678-682.
Madalan, A. M., Melnic, E., Kravtsov, V. C., Simonov, Y. A., Schmidtmann, M., Müller, A., & Andruh, M. (2004). The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine). REVISTA DE CHIMIE, 55(9), 678-682.
Madalan, A. M., Melnic, E., Kravtsov, V. C., Simonov, Y. A., Schmidtmann, M., Müller, A., and Andruh, M. (2004). The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine). REVISTA DE CHIMIE 55, 678-682.
Madalan, A.M., et al., 2004. The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine). REVISTA DE CHIMIE, 55(9), p 678-682.
A.M. Madalan, et al., “The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine)”, REVISTA DE CHIMIE, vol. 55, 2004, pp. 678-682.
Madalan, A.M., Melnic, E., Kravtsov, V.C., Simonov, Y.A., Schmidtmann, M., Müller, A., Andruh, M.: The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine). REVISTA DE CHIMIE. 55, 678-682 (2004).
Madalan, A. M., Melnic, E, Kravtsov, V. C., Simonov, Y. A., Schmidtmann, Marc, Müller, Achim, and Andruh, Marius. “The synthesis, the spectral and structural characterization of two new compounds of the series [Cu(sal)(AA)(ClO4)] (sal = anion of the salicylaldehyde, AA=4,4 '-dimethyl-2,2 '-bispyridil and 2,2 '-bispyrimidine)”. REVISTA DE CHIMIE 55.9 (2004): 678-682.