Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup

Kim B, Balasubramanian R, Perez-Segarra W, Wei A, Decker B, Mattay J (2005)
In: Supramolecular Chemistry. Supramolecular Chemistry, 17(1-2). TAYLOR & FRANCIS LTD: 173-180.

Konferenzbeitrag | Veröffentlicht | Englisch
 
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Autor*in
Kim, Beomseok; Balasubramanian, R.; Perez-Segarra, Waleska; Wei, Alexander; Decker, Björn; Mattay, JochenUniBi
Abstract / Bemerkung
Gold nanoparticles can be encapsulated by various resorcinarene derivatives and assembled into monolayer films at solvent interfaces. Surface charge plays a critical role in both nanoparticle extraction and self-assembly: the degree of monolayer formation and local two-dimensional (2D) order within the nanoparticle arrays is dependent on the chemical nature of the resorcinarene headgroup as well as the presence of other electrolytes. Cluster size distribution analysis can be used to parameterize local 2D order within the arrays in a quantitative manner, based on mean cluster sizes and fractional hexagonal close-packed (hcp) cluster formation. 2D nanoparticle arrays can also be prepared in some cases using Langmuir-Blodgett techniques. These studies demonstrate that resorcinarenes with chemisorptive headgroups promote the self-assembly of well-ordered 2D arrays.
Stichworte
nanoparticles; calixarenes; encapsulation; self-assembly
Erscheinungsjahr
2005
Titel des Konferenzbandes
Supramolecular Chemistry
Band
17
Ausgabe
1-2
Seite(n)
173-180
ISSN
1061-0278
Page URI
https://pub.uni-bielefeld.de/record/1605194

Zitieren

Kim B, Balasubramanian R, Perez-Segarra W, Wei A, Decker B, Mattay J. Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup. In: Supramolecular Chemistry. Supramolecular Chemistry. Vol 17. TAYLOR & FRANCIS LTD; 2005: 173-180.
Kim, B., Balasubramanian, R., Perez-Segarra, W., Wei, A., Decker, B., & Mattay, J. (2005). Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup. Supramolecular Chemistry, Supramolecular Chemistry, 17, 173-180. TAYLOR & FRANCIS LTD. doi:10.1080/10610270412331328961
Kim, B., Balasubramanian, R., Perez-Segarra, W., Wei, A., Decker, B., and Mattay, J. (2005). “Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup” in Supramolecular Chemistry Supramolecular Chemistry, vol. 17, (TAYLOR & FRANCIS LTD), 173-180.
Kim, B., et al., 2005. Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup. In Supramolecular Chemistry. Supramolecular Chemistry. no.17 TAYLOR & FRANCIS LTD, pp. 173-180.
B. Kim, et al., “Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup”, Supramolecular Chemistry, Supramolecular Chemistry, vol. 17, TAYLOR & FRANCIS LTD, 2005, pp.173-180.
Kim, B., Balasubramanian, R., Perez-Segarra, W., Wei, A., Decker, B., Mattay, J.: Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup. Supramolecular Chemistry. Supramolecular Chemistry. 17, p. 173-180. TAYLOR & FRANCIS LTD (2005).
Kim, Beomseok, Balasubramanian, R., Perez-Segarra, Waleska, Wei, Alexander, Decker, Björn, and Mattay, Jochen. “Self-assembly of resorcinarene-stabilized gold nanoparticles: Influence of the macrocyclic headgroup”. Supramolecular Chemistry. TAYLOR & FRANCIS LTD, 2005.Vol. 17. Supramolecular Chemistry. 173-180.