Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides
Schulte T, Siegenthaler KO, Luftmann H, Letzel M, Studer A (2005)
MACROMOLECULES 38(16): 6833-6840.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Schulte, T;
Siegenthaler, KO;
Luftmann, H;
Letzel, MatthiasUniBi;
Studer, A
Einrichtung
Abstract / Bemerkung
Nitroxide-mediated controlled living free radical polymerization of N-isopropylacrylamide using highly sterically hindered 2,2,6,6-tetraethylpiperidin-4-on-N-oxyI 1 is described. In addition, an improved synthesis for nitroxide 1 is presented. Poly-N-isopropylacrylamides (PNIPAMs) prepared are analyzed by multiple-angle laser light scattering. Moreover, the nitroxide-terminated PNIPAMs are characterized using electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS), and Fourier transform ion cyclotron MALDI-MS. Careful MS analysis reveals that chain-end degradation of nitroxide-terminated PNIPAMs occurs during MALDI analysis. A mechanism for chain end degradation is presented.
Erscheinungsjahr
2005
Zeitschriftentitel
MACROMOLECULES
Band
38
Ausgabe
16
Seite(n)
6833-6840
ISSN
0024-9297
eISSN
1520-5835
Page URI
https://pub.uni-bielefeld.de/record/1602825
Zitieren
Schulte T, Siegenthaler KO, Luftmann H, Letzel M, Studer A. Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. MACROMOLECULES. 2005;38(16):6833-6840.
Schulte, T., Siegenthaler, K. O., Luftmann, H., Letzel, M., & Studer, A. (2005). Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. MACROMOLECULES, 38(16), 6833-6840. https://doi.org/10.1021/ma050343n
Schulte, T, Siegenthaler, KO, Luftmann, H, Letzel, Matthias, and Studer, A. 2005. “Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides”. MACROMOLECULES 38 (16): 6833-6840.
Schulte, T., Siegenthaler, K. O., Luftmann, H., Letzel, M., and Studer, A. (2005). Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. MACROMOLECULES 38, 6833-6840.
Schulte, T., et al., 2005. Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. MACROMOLECULES, 38(16), p 6833-6840.
T. Schulte, et al., “Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides”, MACROMOLECULES, vol. 38, 2005, pp. 6833-6840.
Schulte, T., Siegenthaler, K.O., Luftmann, H., Letzel, M., Studer, A.: Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. MACROMOLECULES. 38, 6833-6840 (2005).
Schulte, T, Siegenthaler, KO, Luftmann, H, Letzel, Matthias, and Studer, A. “Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides”. MACROMOLECULES 38.16 (2005): 6833-6840.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar