Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle

Haupt ETK, Wontorra C, Rehder D, Müller A (2005)
CHEMICAL COMMUNICATIONS (31): 3912-3914.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Insight into basic principles of cation transport through ''molecular channels'', and especially details of the related fundamental H2O vehicle function, could be obtained via Li-7 NMR studies of the Li+ uptake/release processes by the unique porous nanocapsule [{(Mo-VI)(Mo5O21)-O-VI(H2O)(6)}(12) {(Mo2O4)-O-V(SO4)}(30)](72-) which behaves as a semi-permeable inorganic membrane open for H2O and small cations; channel traffic as well as internal cavity distribution processes show a strong dependence on ''environmental'' effects such as exerted by solvent properties, the amount of water present, and competing complexing ligands, and end up in a complex equilibrium situation as in biological leak channels.
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CHEMICAL COMMUNICATIONS
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31
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3912-3914
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Haupt ETK, Wontorra C, Rehder D, Müller A. Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle. CHEMICAL COMMUNICATIONS. 2005;(31):3912-3914.
Haupt, E. T. K., Wontorra, C., Rehder, D., & Müller, A. (2005). Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle. CHEMICAL COMMUNICATIONS(31), 3912-3914. doi:10.1039/b506087g
Haupt, E. T. K., Wontorra, C., Rehder, D., and Müller, A. (2005). Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle. CHEMICAL COMMUNICATIONS, 3912-3914.
Haupt, E.T.K., et al., 2005. Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle. CHEMICAL COMMUNICATIONS, (31), p 3912-3914.
E.T.K. Haupt, et al., “Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle”, CHEMICAL COMMUNICATIONS, 2005, pp. 3912-3914.
Haupt, E.T.K., Wontorra, C., Rehder, D., Müller, A.: Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle. CHEMICAL COMMUNICATIONS. 3912-3914 (2005).
Haupt, Erhard T. K., Wontorra, Claudia, Rehder, Dieter, and Müller, Achim. “Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle”. CHEMICAL COMMUNICATIONS 31 (2005): 3912-3914.

6 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Guests on different internal capsule sites exchange with each other and with the outside.
Petina O, Rehder D, Haupt ET, Grego A, Weinstock IA, Merca A, Bögge H, Szakács J, Müller A., Angew Chem Int Ed Engl 50(2), 2011
PMID: 21132826
Confinement and step-wise reopening of channels in an artificial cell/inorganic capsule: a 7Li NMR study.
Haupt ET, Wontorra C, Rehder D, Merca A, Müller A., Chemistry 14(29), 2008
PMID: 18773407
Synthetic ion channels via self-assembly: a route for embedding porous polyoxometalate nanocapsules in lipid bilayer membranes.
Carr R, Weinstock IA, Sivaprasadarao A, Müller A, Aksimentiev A., Nano Lett 8(11), 2008
PMID: 18844424

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