Routes to unique palladium A-frame complexes with a bridging fluoro-ligand

Braun T, Steffen A, Schorlemer V, Neumann B, Stammler H-G (2005)
DALTON TRANSACTIONS (20): 3331-3336.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Braun, T; Steffen, A; Schorlemer, V; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi
Abstract / Bemerkung
Treatment of a toluene solution of [PdMe2(Cy2PCH2PCy2)] ( 1) with pentafluoropyridine in the presence of traces of water affords the generation of the A-frame complexes [(PdMe)(2){mu-kappa(2)(P, P) Cy2PCH2PCy2}(2)(mu-F)][SiMeF4] (2a) and [(PdMe)(2){mu-kappa(2)(P, P) Cy2PCH2PCy2}(2)(mu-F)][OC5NF4] (2b). If the reaction is performed in an NMR tube equipped with a PFA inliner, complex 2b is produced, only. Treatment of 1 with penta fluoropyridine in the presence of an excess water yields the pyridyloxy complex [PdMe(OC5NF4)(Cy2PCH2PCy2)] (3). Compound [(PdMe)(2){mu-kappa(2)(P, P) Cy2PCH2PCy2}(2)(mu-F)][FHF] ( 2c) bearing a bifluoride anion instead of SiMeF4- or OC5NF4- can be generated by reaction of 1 with substoichiometric amounts of Et3N center dot 3HF. The analogous complex [(PdMe)(2){mu-kappa(2)(P, P)Ph2PCH2PPh2}(2)(mu-F)][FHF] ( 5c) has been synthesized by addition of Ph2PCH2PPh2 to a solution of [PdMe2(Me2NCH2CH2NMe2)] ( 4) in THF and subsequent treatment of the reaction mixture with Et3N center dot 3HF. The structure of the A-frame complex 5c has been determined by X-ray crystallography.
Erscheinungsjahr
2005
Zeitschriftentitel
DALTON TRANSACTIONS
Ausgabe
20
Seite(n)
3331-3336
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1602215

Zitieren

Braun T, Steffen A, Schorlemer V, Neumann B, Stammler H-G. Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. DALTON TRANSACTIONS. 2005;(20):3331-3336.
Braun, T., Steffen, A., Schorlemer, V., Neumann, B., & Stammler, H. - G. (2005). Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. DALTON TRANSACTIONS(20), 3331-3336. https://doi.org/10.1039/b509032f
Braun, T, Steffen, A, Schorlemer, V, Neumann, Beate, and Stammler, Hans-Georg. 2005. “Routes to unique palladium A-frame complexes with a bridging fluoro-ligand”. DALTON TRANSACTIONS, no. 20: 3331-3336.
Braun, T., Steffen, A., Schorlemer, V., Neumann, B., and Stammler, H. - G. (2005). Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. DALTON TRANSACTIONS, 3331-3336.
Braun, T., et al., 2005. Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. DALTON TRANSACTIONS, (20), p 3331-3336.
T. Braun, et al., “Routes to unique palladium A-frame complexes with a bridging fluoro-ligand”, DALTON TRANSACTIONS, 2005, pp. 3331-3336.
Braun, T., Steffen, A., Schorlemer, V., Neumann, B., Stammler, H.-G.: Routes to unique palladium A-frame complexes with a bridging fluoro-ligand. DALTON TRANSACTIONS. 3331-3336 (2005).
Braun, T, Steffen, A, Schorlemer, V, Neumann, Beate, and Stammler, Hans-Georg. “Routes to unique palladium A-frame complexes with a bridging fluoro-ligand”. DALTON TRANSACTIONS 20 (2005): 3331-3336.

5 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

The Versatile Behavior of Platinum Alkyne Complexes towards XeF2 : Formation of Fluorovinyl and Fluorido Complexes.
Berger J, Braun T, Ahrens T, Kläring P, Laubenstein R, Braun-Cula B., Chemistry 23(37), 2017
PMID: 28472555
Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.
Ahrens T, Ahrens M, Braun T, Braun B, Herrmann R., Dalton Trans 45(11), 2016
PMID: 26863494
Insertion of CS(2) into iridium-fluorine bonds.
Kläring P, Braun T., Angew Chem Int Ed Engl 52(42), 2013
PMID: 24038624
Unprecedented copper(I) bifluoride complexes: synthesis, characterization and reactivity.
Vergote T, Nahra F, Welle A, Luhmer M, Wouters J, Mager N, Riant O, Leyssens T., Chemistry 18(3), 2012
PMID: 22170626
Palladium fluoro complexes: useful tools to access organometallic metallamacrocycles.
Steffen A, Braun T, Neumann B, Stammler HG., Angew Chem Int Ed Engl 46(45), 2007
PMID: 17924387

105 References

Daten bereitgestellt von Europe PubMed Central.


Pearson, J. Am. Chem. Soc. 85(), 1963

Parr, J. Am. Chem. Soc. 105(), 1983
Absolute electronegativity and hardness correlated with molecular orbital theory.
Pearson RG., Proc. Natl. Acad. Sci. U.S.A. 83(22), 1986
PMID: 16578791

Pagenkopf, Chem. Eur. J. 5(), 1999

Fagnou, Angew. Chem. 114(), 2002

Fagnou, Angew. Chem., Int. Ed. 41(), 2002

Barthazy, Helv. Chim. Acta 82(), 1999

Barthazy, Organometallics 20(), 2001

Barthazy, Organometallics 19(), 2000

Dorta, J. Am. Chem. Soc. 119(), 1997

Mezzetti, Helv. Chim. Acta 85(), 2002
Bridging fluorides and hard/soft mismatch in d6 and d8 complexes: the case of [Tl(mu-F)3Ru(PPh3)3].
Becker C, Kieltsch I, Broggini D, Mezzetti A., Inorg Chem 42(25), 2003
PMID: 14658895

Doherty, Chem. Rev. 91(), 1991

Braun, Chem. Commun. (), 2001

Grushin, Chem. Eur. J. 8(), 2002

Grushin, Angew. Chem. 110(), 1998

Grushin, Angew. Chem., Int. Ed. 37(), 1998

Nilsson, Organometallics 22(), 2003

Kovacs, Organometallics 20(), 2001

Caulton, New J. Chem. 18(), 1994

Flemming, Inorg. Chim. Acta 280(), 1998

Branan, Inorg. Chem. 26(), 1987

Poulton, Inorg. Chem. 33(), 1994

Abu-Hasanayn, Inorg. Chem. 33(), 1994

Tilset, Chem. Commun. (), 1998

Marshall, Organometallics 17(), 1998

Moigno, New J. Chem. 25(), 2001

Moigno, J. Organomet. Chem. 661(), 2002

Roesky, J. Chem. Soc., Dalton Trans. (), 1999

Brammer, Dalton Trans. (), 2003

Jasim, Dalton Trans. (), 2003

Jasim, J. Am. Chem. Soc. 122(), 2000

Jasim, J. Chem. Soc., Dalton Trans. (), 2001

Whittlesey, Chem. Commun. (), 1997

Grushin, Angew. Chem. 114(), 2002

Grushin, Angew. Chem., Int. Ed. 41(), 2002

Noveski, J. Fluorine Chem. 125(), 2003

Pilon, Organometallics 17(), 1998

Roe, Organometallics 19(), 2000

Coleman, J. Chem. Soc., Dalton Trans. (), 1997

Jasim, Organometallics 23(), 2004

Braun, Chem. Commun. (), 2002

Burdeniuc, Chem. Ber./Recl. 130(), 1997

Richmond, Top. Organomet. Chem. 3(), 1999

Kiplinger, Chem. Rev. 94(), 1994

Jones, Dalton Trans. (), 2003

Hofmann, Chem. Ber. 125(), 1992

Sladek, J. Chem. Soc., Dalton Trans. (), 2002

Steffen, Organometallics 24(), 2005
A comparison of C-F and C-H bond activation by zerovalent ni and pt: a density functional study.
Reinhold M, McGrady JE, Perutz RN., J. Am. Chem. Soc. 126(16), 2004
PMID: 15099111

Cronin, Organometallics 16(), 1997

Bach, Organometallics 15(), 1996

Fraser, J. Am. Chem. Soc. 119(), 1997
Synthesis of the elusive (R3P)2MF2 (M = Pd, Pt) complexes.
Yahav A, Goldberg I, Vigalok A., J. Am. Chem. Soc. 125(45), 2003
PMID: 14599181

Yahav, Inorg. Chem. 44(), 2004

Braun, Angew. Chem. 114(), 2002

Braun, Angew. Chem., Int. Ed. 41(), 2002

Noveski, Dalton Trans. (), 2003
Fluorination of [Os3(CO)12] and [Ir4(CO)12].
Hwang IC, Seppelt K., Inorg Chem 42(22), 2003
PMID: 14577779

Balters, Z. Anorg. Allg. Chem. 630(), 2004

Veltheer, J. Am. Chem. Soc. 117(), 1995

Gil-Rubio, J. Chem. Soc., Dalton Trans. (), 1999

Cooper, Organometallics 16(), 1997

Holloway, J. Fluorine Chem. 76(), 1996

Burch, Organometallics 6(), 1987

Ferrando-Miguel, Inorg. Chem. 24(), 2002

Kirkham, Chem. Commun. (), 2001

Barrio, Organometallics 23(), 2004
Hydrogen for fluorine exchange in C6F6 and C6F5H by monomeric [1,3,4-(Me3C)3C5H2]2CeH: experimental and computational studies.
Maron L, Werkema EL, Perrin L, Eisenstein O, Andersen RA., J. Am. Chem. Soc. 127(1), 2005
PMID: 15631477
Synthesis and reactivity of low-coordinate iron(II) fluoride complexes and their use in the catalytic hydrodefluorination of fluorocarbons.
Vela J, Smith JM, Yu Y, Ketterer NA, Flaschenriem CJ, Lachicotte RJ, Holland PL., J. Am. Chem. Soc. 127(21), 2005
PMID: 15913376
The fluoro analogue of Wilkinson's catalyst and unexpected Ph-Cl activation.
Grushin VV, Marshall WJ., J. Am. Chem. Soc. 126(10), 2004
PMID: 15012134

Marshall, Organometallics 23(), 2004
Synthesis and reactivity of fluoro complexes. Part 1. Cyclooctadiene rhodium(I) complexes.
Vicente J, Gil-Rubio J, Bautista D., Inorg Chem 40(12), 2001
PMID: 11375671

Vicente, Inorg. Chem. 18(), 2004

Gil-Rubio, Angew. Chem. 112(), 2000

Gil-Rubio, Angew. Chem., Int. Ed. 39(), 2000

Gorol, Eur. J. Inorg. Chem. (), 2004

Cámpora, Organometallics 24(), 2004

Kellenberger, J. Am. Chem. Soc. 107(), 1985

Young, J. Am. Chem. Soc. 110(), 1988

Klanberg, Inorg. Chem. 7(), 1968

Adamson, J. Fluorine Chem. 76(), 1996

Cooper, New. J. Chem. (), 1998

Seppelt, Angew. Chem. 104(), 1992

Seppelt, Angew. Chem., Int. Ed. 31(), 1992

Braun, Inorg. Chem. Commun. 6(), 2003

de, Organometallics 8(), 1989
Facile reductive elimination of ethane from strained dimethylpalladium(II) complexes.
Reid SM, Mague JT, Fink MJ., J. Am. Chem. Soc. 123(17), 2001
PMID: 11457160

Noveski, Dalton Trans. (), 2004

Bennett, J. Am. Chem. Soc. 116(), 1994

Sharma, J. Org. Chem. 48(), 1983

Balch, J. Am. Chem. Soc. 103(), 1981

Lee, Organometallics 1(), 1982

Puddephatt, J. Am. Chem. Soc. 105(), 1983

Emsley, Chem. Soc. Rev. 9(), 1980

Hibbert, Adv. Phys. Org. Chem. 26(), 1990

Olmstead, Inorg. Chim. Acta 52(), 1981

Stockland,, Organometallics 20(), 2001

Stockland,, Organometallics 16(), 1997

Hewertson, J. Chem. Soc. (), 1962
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 16193151
PubMed | Europe PMC

Suchen in

Google Scholar