Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound
Müller A, Talismanov S, Kögerler P, Bögge H, Schmidtmann M, Tsukerblat B (2005)
JOURNAL OF CLUSTER SCIENCE 16(3): 391-396.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Müller, AchimUniBi ;
Talismanov, S;
Kögerler, Paul;
Bögge, HartmutUniBi;
Schmidtmann, Marc;
Tsukerblat, B
Einrichtung
Abstract / Bemerkung
A planar network consisting of {Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-6(III)} cluster entities that are interlinked to layers via {Fe-II(H2O)(4)}(2+) groups is formed stepwise from building Units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: {MoNO}(3+) Mo-V, Mo-VI, Fe-II, and Fe-III. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.
Stichworte
extended structure;
mixed-valence;
magnetochemistry;
polyoxometalates;
molybdenum;
building block;
iron
Erscheinungsjahr
2005
Zeitschriftentitel
JOURNAL OF CLUSTER SCIENCE
Band
16
Ausgabe
3
Seite(n)
391-396
ISSN
1040-7278
eISSN
1572-8862
Page URI
https://pub.uni-bielefeld.de/record/1601097
Zitieren
Müller A, Talismanov S, Kögerler P, Bögge H, Schmidtmann M, Tsukerblat B. Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound. JOURNAL OF CLUSTER SCIENCE. 2005;16(3):391-396.
Müller, A., Talismanov, S., Kögerler, P., Bögge, H., Schmidtmann, M., & Tsukerblat, B. (2005). Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound. JOURNAL OF CLUSTER SCIENCE, 16(3), 391-396. https://doi.org/10.1007/s10876-005-0008-y
Müller, Achim, Talismanov, S, Kögerler, Paul, Bögge, Hartmut, Schmidtmann, Marc, and Tsukerblat, B. 2005. “Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound”. JOURNAL OF CLUSTER SCIENCE 16 (3): 391-396.
Müller, A., Talismanov, S., Kögerler, P., Bögge, H., Schmidtmann, M., and Tsukerblat, B. (2005). Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound. JOURNAL OF CLUSTER SCIENCE 16, 391-396.
Müller, A., et al., 2005. Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound. JOURNAL OF CLUSTER SCIENCE, 16(3), p 391-396.
A. Müller, et al., “Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound”, JOURNAL OF CLUSTER SCIENCE, vol. 16, 2005, pp. 391-396.
Müller, A., Talismanov, S., Kögerler, P., Bögge, H., Schmidtmann, M., Tsukerblat, B.: Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound. JOURNAL OF CLUSTER SCIENCE. 16, 391-396 (2005).
Müller, Achim, Talismanov, S, Kögerler, Paul, Bögge, Hartmut, Schmidtmann, Marc, and Tsukerblat, B. “Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A(infinity)(2)[({Mo-17(NO)(2)}(3){Mo-2(V)}(3){Fe-III}(6))(Fe-1.5(II))]-t ype layer compound”. JOURNAL OF CLUSTER SCIENCE 16.3 (2005): 391-396.
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