Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu)
Weber L, Bayer P, Noveski G, Stammler H-G, Neumann B (2006)
European Journal of Inorganic Chemistry 2006(11): 2299-2305.
Zeitschriftenaufsatz
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Autor*in
Weber, LotharUniBi;
Bayer, Philipp;
Noveski, Gabriel;
Stammler, Hans-GeorgUniBi;
Neumann, BeateUniBi
Einrichtung
Abstract / Bemerkung
The reaction of the vinylidene complexes [(C5H5)(CO)(NO)W=C=C(H)RI (10a: R = tBu; 10b: R = Ph) with the arsaalkene tBuC(O)-As=C(NMe2)(2) (11) afforded the novel eta(2)-1-arsaallene complexes [eta(2)-{tBuC(O)-As=C=C(H)R}W(CO)(NO)-C5H5] (13: R = tBu; 15: R = Ph). Similarly, treatment of 10a with the ferrioarsaalkene [(C5Me5)(CO)(2)Fe-As=C(NMe2)(2)] (12) led to the formation of [eta(2)-{[(C5Me5)(CO)(2)Fe]-As=C=C(H)tBu}W(CO)(NO)(C5H5)] (14), whereas combination of 12 and 1 Ob yielded the carbene complex [(C5H5) (CO) (NO)W=C(NMe2)C(Ph)=C(H)NMe2] (16) in high yield instead of the anticipated arsaallene complex. The novel compounds 13, 14, 15 and 16 were characterised by elemental analyses and by means of spectroscopy (IR, H-1, C-13 NMR). Moreover, the molecular structures of 14 and 15 were elucidated by X-ray diffraction analyses. (c) Wiley-VCH Verlag GmbH & Co. KGaA.
Stichworte
heteroallene ligands;
arsaalkenes;
tungsten;
vinylidene complexes
Erscheinungsjahr
2006
Zeitschriftentitel
European Journal of Inorganic Chemistry
Band
2006
Ausgabe
11
Seite(n)
2299-2305
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/1598914
Zitieren
Weber L, Bayer P, Noveski G, Stammler H-G, Neumann B. Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu). European Journal of Inorganic Chemistry. 2006;2006(11):2299-2305.
Weber, L., Bayer, P., Noveski, G., Stammler, H. - G., & Neumann, B. (2006). Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu). European Journal of Inorganic Chemistry, 2006(11), 2299-2305. https://doi.org/10.1002/ejic.200600094
Weber, Lothar, Bayer, Philipp, Noveski, Gabriel, Stammler, Hans-Georg, and Neumann, Beate. 2006. “Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu)”. European Journal of Inorganic Chemistry 2006 (11): 2299-2305.
Weber, L., Bayer, P., Noveski, G., Stammler, H. - G., and Neumann, B. (2006). Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu). European Journal of Inorganic Chemistry 2006, 2299-2305.
Weber, L., et al., 2006. Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu). European Journal of Inorganic Chemistry, 2006(11), p 2299-2305.
L. Weber, et al., “Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu)”, European Journal of Inorganic Chemistry, vol. 2006, 2006, pp. 2299-2305.
Weber, L., Bayer, P., Noveski, G., Stammler, H.-G., Neumann, B.: Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu). European Journal of Inorganic Chemistry. 2006, 2299-2305 (2006).
Weber, Lothar, Bayer, Philipp, Noveski, Gabriel, Stammler, Hans-Georg, and Neumann, Beate. “Reactivity of the Inversely Polarized Arsaalkenes R–As=C(NMe2)2 {R = t-BuC(O), [η5-C5Me5)(CO)2Fe]} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, t-Bu)”. European Journal of Inorganic Chemistry 2006.11 (2006): 2299-2305.
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