Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange

Tsukerblat B, Tarantul A, Müller A (2006)
JOURNAL OF CHEMICAL PHYSICS 125(5): 054714.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The low temperature EPR spectra of the unique nanometer-scale molecular magnet V-15 are analyzed within the three-spin model preserving trigonal symmetry. The Hamiltonian includes isotropic and antisymmetric (AS) exchange interactions introduced by Dzyaloshinsky (Zh. Eksp. Teor. Fiz. 32, 1547 (1957) [Sov. Phys. JETP 5, 1259 (1957)]) and [Moria Phys. Rev. 120, 91 (1960)]. With the aid of pseudoangular momentum representation the exact selection rules for the EPR transitions are deduced. AS exchange in the frustrated triangular system gives rise to a first order zero-field splitting of two low lying spin doublets and to a second order splitting of the excited quadruplet. This leads to a peculiar series of strong intramultiplet transitions and weak intermultiplet transitions. We show that the intramultiplet transitions are allowed only when the vector of the AS exchange is normal to the plane of vanadium triangle, but the series of weak intermultiplet transitions are a consequence of the in-plane part of the AS exchange. We have revealed a special temperature dependence of the EPR pattern with a peculiar shape of the full spectrum. Experimental data on high-frequency EPR of V-15 at ultralow temperature are discussed. (c) 2006 American Institute of Physics.
Erscheinungsjahr
2006
Zeitschriftentitel
JOURNAL OF CHEMICAL PHYSICS
Band
125
Ausgabe
5
Seite(n)
054714
ISSN
0021-9606
Page URI
https://pub.uni-bielefeld.de/record/1598291

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Tsukerblat B, Tarantul A, Müller A. Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange. JOURNAL OF CHEMICAL PHYSICS. 2006;125(5):054714.
Tsukerblat, B., Tarantul, A., & Müller, A. (2006). Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange. JOURNAL OF CHEMICAL PHYSICS, 125(5), 054714. doi:10.1063/1.2227390
Tsukerblat, B., Tarantul, A., and Müller, A. (2006). Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange. JOURNAL OF CHEMICAL PHYSICS 125, 054714.
Tsukerblat, B., Tarantul, A., & Müller, A., 2006. Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange. JOURNAL OF CHEMICAL PHYSICS, 125(5), p 054714.
B. Tsukerblat, A. Tarantul, and A. Müller, “Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange”, JOURNAL OF CHEMICAL PHYSICS, vol. 125, 2006, pp. 054714.
Tsukerblat, B., Tarantul, A., Müller, A.: Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange. JOURNAL OF CHEMICAL PHYSICS. 125, 054714 (2006).
Tsukerblat, Boris, Tarantul, Alex, and Müller, Achim. “Low temperature EPR spectra of the mesoscopic cluster V-15: The role of antisymmetric exchange”. JOURNAL OF CHEMICAL PHYSICS 125.5 (2006): 054714.

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