Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes
Liu T, Imber B, Diemann E, Liu G, Cokleski K, li HL, Chen Z, Müller A (2006)
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128(49): 15914-15920.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Liu, Tianbo;
Imber, Brandon;
Diemann, EkkehardUniBi;
Liu, Guang;
Cokleski, Katrina;
li, Huin Li;
Chen, Zhiqiang;
Müller, AchimUniBi ![](https://pub.uni-bielefeld.de/images/icon_orcid.png)
![](https://pub.uni-bielefeld.de/images/icon_orcid.png)
Einrichtung
Abstract / Bemerkung
The solution behavior of the largest inorganic acid known thus far, the neutral, spherical iron/molybdenum/oxide nanocluster {Mo72Fe30} (equivalent to{(Mo-VI)Mo-5(VI)}(12)Fe-30(III) 1a), including the pH-controlled deprotonation, is reported. The acidic properties are due to the 30 peripheral, weakly acidic Fe-III(H2O) groups that form a unique Archimedean solid with all edges and dihedral angles being equal, the icosidodecahedron, and therefore an "isotropic" surface. Interestingly, the aqueous solutions are stable even for months because of the inertness of the spherical solutes and the presence of the hard FeIII and Mo-VI centers. The stability can be nicely proven by the very characteristic Raman spectrum showing, because of the (approximately) icosahedral symmetry, only a few lines. Whereas the {Mo72Fe30} clusters exist as discrete, almost neutral, molecules in aqueous solution at pH < 2.9, they get deprotonated and self-associate into single-layer blackberry-type structures at higher pH while the assembly process (i.e., the size of the final species) can be controlled by the pH values; this allows the deliberate generation of differently sized nanoparticles, a long-term goal in nanoscience. The average hydrodynamic radius (R-h) of the self-assembled structures decreases monotonically with increasing number of charges on the {Mo72Fe30} macroanions (from similar to 45 nm at pH similar to 3.0 to similar to 15 nm at pH approximate to 6.6), as studied by laser light scattering and TEM techniques. The {Mo72Fe30} macroions with high-stability tunable charges/surfaces, equal shape, and masses provide models for the understanding of more complex polyelectrolyte solutions while the controllable association and dissociation reported here of the assembled soft magnetic materials with tuneable sizes could be interesting for practical applications.
Erscheinungsjahr
2006
Zeitschriftentitel
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Band
128
Ausgabe
49
Seite(n)
15914-15920
ISSN
0002-7863
eISSN
1520-5126
Page URI
https://pub.uni-bielefeld.de/record/1596756
Zitieren
Liu T, Imber B, Diemann E, et al. Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006;128(49):15914-15920.
Liu, T., Imber, B., Diemann, E., Liu, G., Cokleski, K., li, H. L., Chen, Z., et al. (2006). Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(49), 15914-15920. https://doi.org/10.1021/ja066133n
Liu, Tianbo, Imber, Brandon, Diemann, Ekkehard, Liu, Guang, Cokleski, Katrina, li, Huin Li, Chen, Zhiqiang, and Müller, Achim. 2006. “Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128 (49): 15914-15920.
Liu, T., Imber, B., Diemann, E., Liu, G., Cokleski, K., li, H. L., Chen, Z., and Müller, A. (2006). Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128, 15914-15920.
Liu, T., et al., 2006. Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(49), p 15914-15920.
T. Liu, et al., “Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes”, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 128, 2006, pp. 15914-15920.
Liu, T., Imber, B., Diemann, E., Liu, G., Cokleski, K., li, H.L., Chen, Z., Müller, A.: Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 128, 15914-15920 (2006).
Liu, Tianbo, Imber, Brandon, Diemann, Ekkehard, Liu, Guang, Cokleski, Katrina, li, Huin Li, Chen, Zhiqiang, and Müller, Achim. “Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128.49 (2006): 15914-15920.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
38 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Expanding the Schulze-Hardy Rule and the Hofmeister Series to Nanometer-Scaled Hydrophilic Macroions.
Chu Y, Chen J, Haso F, Gao Y, Szymanowski JES, Burns PC, Liu T., Chemistry 24(21), 2018
PMID: 29582490
Chu Y, Chen J, Haso F, Gao Y, Szymanowski JES, Burns PC, Liu T., Chemistry 24(21), 2018
PMID: 29582490
Unique Symmetry-Breaking Phenomenon during the Self-assembly of Macroions Elucidated by Simulation.
Liu Z, Liu T, Tsige M., Sci Rep 8(1), 2018
PMID: 30166571
Liu Z, Liu T, Tsige M., Sci Rep 8(1), 2018
PMID: 30166571
Chain length dependent alkane/β-cyclodextrin nonamphiphilic supramolecular building blocks.
Zhou C, Huang J, Yan Y., Soft Matter 12(5), 2016
PMID: 26660592
Zhou C, Huang J, Yan Y., Soft Matter 12(5), 2016
PMID: 26660592
Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K(+) Ion Channels.
Gao Y, Szymanowski JE, Sun X, Burns PC, Liu T., Angew Chem Int Ed Engl 55(24), 2016
PMID: 27105921
Gao Y, Szymanowski JE, Sun X, Burns PC, Liu T., Angew Chem Int Ed Engl 55(24), 2016
PMID: 27105921
Self-patterning porous films of giant vesicles of {Mo72Fe30}(DODMA)3 complexes as frameworks.
Sun H, Yang Q, Hao J., Adv Colloid Interface Sci 235(), 2016
PMID: 27233525
Sun H, Yang Q, Hao J., Adv Colloid Interface Sci 235(), 2016
PMID: 27233525
Elucidating the Origin of the Attractive Force among Hydrophilic Macroions.
Liu Z, Liu T, Tsige M., Sci Rep 6(), 2016
PMID: 27215898
Liu Z, Liu T, Tsige M., Sci Rep 6(), 2016
PMID: 27215898
Modification of the Solution Behavior of Pd12 L24 Metal-Organic Nanocages via PEGylation.
Li H, Luo J, Liu T., Chemistry 22(50), 2016
PMID: 27797422
Li H, Luo J, Liu T., Chemistry 22(50), 2016
PMID: 27797422
Hedgehog-shaped {Mo368} cluster: unique electronic/structural properties, surfactant encapsulation and related self-assembly into vesicles and films.
Garai S, Merca A, Bhowmik S, El Moll H, Li H, Haso F, Nogueira H, Liu T, Wu L, Gouzerh P, Müller A., Soft Matter 11(12), 2015
PMID: 25629447
Garai S, Merca A, Bhowmik S, El Moll H, Li H, Haso F, Nogueira H, Liu T, Wu L, Gouzerh P, Müller A., Soft Matter 11(12), 2015
PMID: 25629447
Crown-shaped tungstogermanates as solvent-controlled dual systems in the formation of vesicle-like assemblies.
Artetxe B, Reinoso S, San Felices L, Gutiérrez-Zorrilla JM, García JA, Haso F, Liu T, Vicent C., Chemistry 21(21), 2015
PMID: 25916974
Artetxe B, Reinoso S, San Felices L, Gutiérrez-Zorrilla JM, García JA, Haso F, Liu T, Vicent C., Chemistry 21(21), 2015
PMID: 25916974
Self-Recognition Between Two Almost Identical Macroions During Their Assembly: The Effects of pH and Temperature.
Haso F, Li D, Garai S, Pigga JM, Liu T., Chemistry 21(38), 2015
PMID: 26332230
Haso F, Li D, Garai S, Pigga JM, Liu T., Chemistry 21(38), 2015
PMID: 26332230
Supramolecular Assembly of Poly(propyleneimine) Dendrimers Driven By Simple Monovalent Counterions.
Eghtesadi SA, Haso F, Kashfipour MA, Lillard RS, Liu T., Chemistry 21(51), 2015
PMID: 26548381
Eghtesadi SA, Haso F, Kashfipour MA, Lillard RS, Liu T., Chemistry 21(51), 2015
PMID: 26548381
Keplerate cluster (Mo-132) mediated electrostatic assembly of nanoparticles.
Gooch J, Jalan AA, Jones S, Hine CR, Alam R, Garai S, Maye MM, Müller A, Zubieta J., J Colloid Interface Sci 432(), 2014
PMID: 25086388
Gooch J, Jalan AA, Jones S, Hine CR, Alam R, Garai S, Maye MM, Müller A, Zubieta J., J Colloid Interface Sci 432(), 2014
PMID: 25086388
Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate Keplerate clusters and their supramolecular assemblies.
Robbins PJ, Surman AJ, Thiel J, Long DL, Cronin L., Chem Commun (Camb) 49(19), 2013
PMID: 23364185
Robbins PJ, Surman AJ, Thiel J, Long DL, Cronin L., Chem Commun (Camb) 49(19), 2013
PMID: 23364185
Redox-controlled helical self-assembly of a polyoxometalate complex.
Zhang J, Li W, Wu C, Li B, Zhang J, Wu L., Chemistry 19(25), 2013
PMID: 23616444
Zhang J, Li W, Wu C, Li B, Zhang J, Wu L., Chemistry 19(25), 2013
PMID: 23616444
Sheet-like assemblies of spherical particles with point-symmetrical patches.
Mani E, Sanz E, Roy S, Dijkstra M, Groenewold J, Kegel WK., J Chem Phys 136(14), 2012
PMID: 22502542
Mani E, Sanz E, Roy S, Dijkstra M, Groenewold J, Kegel WK., J Chem Phys 136(14), 2012
PMID: 22502542
Controllable self-assembly of organic-inorganic amphiphiles containing Dawson polyoxometalate clusters.
Yin P, Pradeep CP, Zhang B, Li FY, Lydon C, Rosnes MH, Li D, Bitterlich E, Xu L, Cronin L, Liu T., Chemistry 18(26), 2012
PMID: 22618885
Yin P, Pradeep CP, Zhang B, Li FY, Lydon C, Rosnes MH, Li D, Bitterlich E, Xu L, Cronin L, Liu T., Chemistry 18(26), 2012
PMID: 22618885
Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate-organic hybrids as novel surfactants.
Yin P, Li D, Liu T., Chem Soc Rev 41(22), 2012
PMID: 22858584
Yin P, Li D, Liu T., Chem Soc Rev 41(22), 2012
PMID: 22858584
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry.
Müller A, Gouzerh P., Chem Soc Rev 41(22), 2012
PMID: 22948798
Müller A, Gouzerh P., Chem Soc Rev 41(22), 2012
PMID: 22948798
Chemical adaptability: the integration of different kinds of matter into giant molecular metal oxides.
Müller A, Merca A, Al-Karawi AJ, Garai S, Bögge H, Hou G, Wu L, Haupt ET, Rehder D, Haso F, Liu T., Chemistry 18(51), 2012
PMID: 23180718
Müller A, Merca A, Al-Karawi AJ, Garai S, Bögge H, Hou G, Wu L, Haupt ET, Rehder D, Haso F, Liu T., Chemistry 18(51), 2012
PMID: 23180718
Porous capsules {(M)M(5)}(12)Fe(III) (30) (M=Mo(VI), W(VI)): sphere surface supramolecular chemistry with 20 ammonium ions, related solution properties, and tuning of magnetic exchange interactions.
Todea AM, Merca A, Bögge H, Glaser T, Pigga JM, Langston ML, Liu T, Prozorov R, Luban M, Schröder C, Casey WH, Müller A., Angew Chem Int Ed Engl 49(3), 2010
PMID: 20013836
Todea AM, Merca A, Bögge H, Glaser T, Pigga JM, Langston ML, Liu T, Prozorov R, Luban M, Schröder C, Casey WH, Müller A., Angew Chem Int Ed Engl 49(3), 2010
PMID: 20013836
Development of a building block strategy to access gigantic nanoscale heteropolyoxotungstates by using SeO3(2-) as a template linker.
Yan J, Long DL, Cronin L., Angew Chem Int Ed Engl 49(24), 2010
PMID: 20437434
Yan J, Long DL, Cronin L., Angew Chem Int Ed Engl 49(24), 2010
PMID: 20437434
Cation mediated self-assembly of inorganic cluster anion building blocks.
Wang Y, Weinstock IA., Dalton Trans 39(27), 2010
PMID: 20520910
Wang Y, Weinstock IA., Dalton Trans 39(27), 2010
PMID: 20520910
Like likes like: counterion-mediated attraction in macroionic and colloidal interaction.
Ise N., Phys Chem Chem Phys 12(35), 2010
PMID: 20623060
Ise N., Phys Chem Chem Phys 12(35), 2010
PMID: 20623060
Magnetic {Mo72Fe30}-embedded hybrid nanocapsules.
Cui J, Fan D, Hao J., J Colloid Interface Sci 330(2), 2009
PMID: 19027122
Cui J, Fan D, Hao J., J Colloid Interface Sci 330(2), 2009
PMID: 19027122
Unprecedented and differently applicable pentagonal units in a dynamic library: a keplerate of the type {(W)W5}12{Mo2}30.
Schäffer C, Merca A, Bögge H, Todea AM, Kistler ML, Liu T, Thouvenot R, Gouzerh P, Müller A., Angew Chem Int Ed Engl 48(1), 2009
PMID: 19035609
Schäffer C, Merca A, Bögge H, Todea AM, Kistler ML, Liu T, Thouvenot R, Gouzerh P, Müller A., Angew Chem Int Ed Engl 48(1), 2009
PMID: 19035609
Minerals as molecules--use of aqueous oxide and hydroxide clusters to understand geochemical reactions.
Casey WH, Rustad JR, Spiccia L., Chemistry 15(18), 2009
PMID: 19347896
Casey WH, Rustad JR, Spiccia L., Chemistry 15(18), 2009
PMID: 19347896
Supramolecular chemistry on a cluster surface: fixation/complexation of potassium and ammonium ions with crown-ether-like rings.
Müller A, Sousa FL, Merca A, Bögge H, Miró P, Fernández JA, Poblet JM, Bo C., Angew Chem Int Ed Engl 48(32), 2009
PMID: 19582749
Müller A, Sousa FL, Merca A, Bögge H, Miró P, Fernández JA, Poblet JM, Bo C., Angew Chem Int Ed Engl 48(32), 2009
PMID: 19582749
Counterion distribution around hydrophilic molecular macroanions: the source of the attractive force in self-assembly.
Pigga JM, Kistler ML, Shew CY, Antonio MR, Liu T., Angew Chem Int Ed Engl 48(35), 2009
PMID: 19630043
Pigga JM, Kistler ML, Shew CY, Antonio MR, Liu T., Angew Chem Int Ed Engl 48(35), 2009
PMID: 19630043
Hierarchical self-assembly of metallo-supramolecular nanospheres.
Baytekin HT, Baytekin B, Schulz A, Schalley CA., Small 5(2), 2009
PMID: 19051183
Baytekin HT, Baytekin B, Schulz A, Schalley CA., Small 5(2), 2009
PMID: 19051183
Phase stability of Keplerate-type polyoxomolybdates controlled by added cationic surfactant.
Fan D, Hao J., J Colloid Interface Sci 333(2), 2009
PMID: 19232628
Fan D, Hao J., J Colloid Interface Sci 333(2), 2009
PMID: 19232628
Molybdenum-oxide based unique polyprotic nanoacids showing different deprotonations and related assembly processes in solution.
Kistler ML, Liu T, Gouzerh P, Todea AM, Müller A., Dalton Trans (26), 2009
PMID: 19562168
Kistler ML, Liu T, Gouzerh P, Todea AM, Müller A., Dalton Trans (26), 2009
PMID: 19562168
Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science.
Proust A, Thouvenot R, Gouzerh P., Chem Commun (Camb) (16), 2008
PMID: 18401495
Proust A, Thouvenot R, Gouzerh P., Chem Commun (Camb) (16), 2008
PMID: 18401495
Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size.
Merca A, Bögge H, Schmidtmann M, Zhou Y, Haupt ET, Sarker MK, Hill CL, Müller A., Chem Commun (Camb) (8), 2008
PMID: 18283345
Merca A, Bögge H, Schmidtmann M, Zhou Y, Haupt ET, Sarker MK, Hill CL, Müller A., Chem Commun (Camb) (8), 2008
PMID: 18283345
Self-patterning of hydrophobic materials into highly ordered honeycomb nanostructures at the air/water interface.
Fan D, Jia X, Tang P, Hao J, Liu T., Angew Chem Int Ed Engl 46(18), 2007
PMID: 17378002
Fan D, Jia X, Tang P, Hao J, Liu T., Angew Chem Int Ed Engl 46(18), 2007
PMID: 17378002
Extending the {(Mo)MO5}12M30 capsule keplerate sequence: a {Cr30} cluster of S=3/2 metal centers with a {Na(H2O)12} encapsulate.
Todea AM, Merca A, Bögge H, van Slageren J, Dressel M, Engelhardt L, Luban M, Glaser T, Henry M, Müller A., Angew Chem Int Ed Engl 46(32), 2007
PMID: 17628480
Todea AM, Merca A, Bögge H, van Slageren J, Dressel M, Engelhardt L, Luban M, Glaser T, Henry M, Müller A., Angew Chem Int Ed Engl 46(32), 2007
PMID: 17628480
Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: simultaneous interaction of porous capsules with molecular plugs and passing cations.
Merca A, Haupt ET, Mitra T, Bögge H, Rehder D, Müller A., Chemistry 13(27), 2007
PMID: 17639541
Merca A, Haupt ET, Mitra T, Bögge H, Rehder D, Müller A., Chemistry 13(27), 2007
PMID: 17639541
Self-association based on interfacial structured water leads to {Mo154}approximately 1165 super clusters: a dielectric study.
Oleinikova A, Weingärtner H, Chaplin M, Diemann E, Bögge H, Müller A., Chemphyschem 8(5), 2007
PMID: 17335107
Oleinikova A, Weingärtner H, Chaplin M, Diemann E, Bögge H, Müller A., Chemphyschem 8(5), 2007
PMID: 17335107
Nanometer-sized molybdenum-iron oxide capsule-surface modifications: external and internal.
Müller A, Bögge H, Sousa FL, Schmidtmann M, Kurth DG, Volkmer D, van Slageren J, Dressel M, Kistler ML, Liu T., Small 3(6), 2007
PMID: 17385209
Müller A, Bögge H, Sousa FL, Schmidtmann M, Kurth DG, Volkmer D, van Slageren J, Dressel M, Kistler ML, Liu T., Small 3(6), 2007
PMID: 17385209
References
Daten bereitgestellt von Europe PubMed Central.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 17147404
PubMed | Europe PMC
Suchen in