High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption

Turchanin A, El-Desawy M, Gölzhäuser A (2007)
Applied Physics Letters 90(5): 053102.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
An extremely high thermal stability of electron cross-linked biphenyl self-assembled monolayers (SAMs) is reported. The authors found that pristine biphenylthiol SAMs desorb at similar to 400 K from gold surfaces, which is induced by a breaking of C-S bonds. Despite of a similar bond cleavage in cross-linked SAMs, these remain on the surface up to 1000 K, which is the highest temperature reported for a SAM. When patterns of pristine and cross-linked SAMs are heated, the pristine regions desorb, and the cross-linked regions remain on the surface. The authors show that this thermal desorption lithography can be utilized for the fabrication of molecular surface nanostructures.
Erscheinungsjahr
2007
Zeitschriftentitel
Applied Physics Letters
Band
90
Ausgabe
5
Art.-Nr.
053102
ISSN
0003-6951
Page URI
https://pub.uni-bielefeld.de/record/1595903

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Turchanin A, El-Desawy M, Gölzhäuser A. High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption. Applied Physics Letters. 2007;90(5): 053102.
Turchanin, A., El-Desawy, M., & Gölzhäuser, A. (2007). High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption. Applied Physics Letters, 90(5), 053102. https://doi.org/10.1063/1.2437091
Turchanin, Andrey, El-Desawy, Mohamed, and Gölzhäuser, Armin. 2007. “High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption”. Applied Physics Letters 90 (5): 053102.
Turchanin, A., El-Desawy, M., and Gölzhäuser, A. (2007). High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption. Applied Physics Letters 90:053102.
Turchanin, A., El-Desawy, M., & Gölzhäuser, A., 2007. High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption. Applied Physics Letters, 90(5): 053102.
A. Turchanin, M. El-Desawy, and A. Gölzhäuser, “High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption”, Applied Physics Letters, vol. 90, 2007, : 053102.
Turchanin, A., El-Desawy, M., Gölzhäuser, A.: High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption. Applied Physics Letters. 90, : 053102 (2007).
Turchanin, Andrey, El-Desawy, Mohamed, and Gölzhäuser, Armin. “High thermal stability of cross-linked aromatic self-assembled monolayers: Nanopatterning via selective thermal desorption”. Applied Physics Letters 90.5 (2007): 053102.
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