Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds

Waske PA, Tzvetkov NT, Mattay J (2007)
SYNLETT 2007(5): 0669-0685.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
The concept of intramolecular radical ion cyclization reactions by photoinduced electron transfer (PET) is a powerful tool for constructing complex carbocyclic and heterocyclic ring systems. In this account we describe Our earlier investigations in this field followed by the development of new approaches to the synthesis of polycyclic compounds. Radical ions generated by single-electron transfer (SET) from suitable neutral molecules are used as decisive intermediates in a wide range of interesting cyclization processes and reactions. Various synthetic strategies are presented involving radical anionic or radical cationic species generated by reductive and oxidative PET, respectively.
Stichworte
oxidative photoinduced electron transfer; electron transfer; PET; cyclopropyl silyl ethers; silyl enol ethers; tandem rearrangement-cyclization reactions; cyclopropyl ketones; reductive photoinduced
Erscheinungsjahr
2007
Zeitschriftentitel
SYNLETT
Band
2007
Ausgabe
5
Seite(n)
0669-0685
ISSN
0936-5214
eISSN
1437-2096
Page URI
https://pub.uni-bielefeld.de/record/1594133

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Waske PA, Tzvetkov NT, Mattay J. Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds. SYNLETT. 2007;2007(5):0669-0685.
Waske, P. A., Tzvetkov, N. T., & Mattay, J. (2007). Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds. SYNLETT, 2007(5), 0669-0685. doi:10.1055/s-2007-970777
Waske, P. A., Tzvetkov, N. T., and Mattay, J. (2007). Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds. SYNLETT 2007, 0669-0685.
Waske, P.A., Tzvetkov, N.T., & Mattay, J., 2007. Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds. SYNLETT, 2007(5), p 0669-0685.
P.A. Waske, N.T. Tzvetkov, and J. Mattay, “Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds”, SYNLETT, vol. 2007, 2007, pp. 0669-0685.
Waske, P.A., Tzvetkov, N.T., Mattay, J.: Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds. SYNLETT. 2007, 0669-0685 (2007).
Waske, Prashant A., Tzvetkov, Nikolay T., and Mattay, Jochen. “Rearrangement and cyclization reactions by photoinduced electron transfer: New approaches for the synthesis of polycyclic compounds”. SYNLETT 2007.5 (2007): 0669-0685.