Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical

Zhou J, Garand E, Eisfeld W, Neumark DM (2007)
JOURNAL OF CHEMICAL PHYSICS 127(3): 034304.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
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Abstract / Bemerkung
High resolution photoelectron spectra of the 1-propynyl and 1-propynyl-d(3) anions acquired with slow electron velocity-map imaging are presented. The electron affinity is determined to be 2.7355 +/- 0.0010 eV for the 1-propynyl radical and 2.7300 +/- 0.0010 eV for 1-propynyl-d(3). Several vibronic transitions are observed and assigned using the isotopic shifts and results from ab initio calculations. Good agreement between experimental spectra and calculations suggests a C-3v geometry for the 1-propynyl radical. No evidence is found for strong vibronic coupling between the ground electronic state and the low-lying first excited state. (C) 2007 American Institute of Physics.
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF CHEMICAL PHYSICS
Band
127
Ausgabe
3
Seite(n)
034304
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Zhou J, Garand E, Eisfeld W, Neumark DM. Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. JOURNAL OF CHEMICAL PHYSICS. 2007;127(3):034304.
Zhou, J., Garand, E., Eisfeld, W., & Neumark, D. M. (2007). Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. JOURNAL OF CHEMICAL PHYSICS, 127(3), 034304. doi:10.1063/1.2748399
Zhou, J., Garand, E., Eisfeld, W., and Neumark, D. M. (2007). Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. JOURNAL OF CHEMICAL PHYSICS 127, 034304.
Zhou, J., et al., 2007. Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. JOURNAL OF CHEMICAL PHYSICS, 127(3), p 034304.
J. Zhou, et al., “Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical”, JOURNAL OF CHEMICAL PHYSICS, vol. 127, 2007, pp. 034304.
Zhou, J., Garand, E., Eisfeld, W., Neumark, D.M.: Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical. JOURNAL OF CHEMICAL PHYSICS. 127, 034304 (2007).
Zhou, Jia, Garand, Etienne, Eisfeld, Wolfgang, and Neumark, Daniel M. “Slow electron velocity-map imaging spectroscopy of the 1-propynyl radical”. JOURNAL OF CHEMICAL PHYSICS 127.3 (2007): 034304.

13 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

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