Synthetic routes towards cryptophycin unit A diastereomers

Eissler S, Neumann B, Stammler H-G, Sewald N (2008)
SYNLETT 2008(2): 273-277.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Unit A of cryptophycin 1 is a delta-hydroxy acid with four stereogenic centres. Our unit A synthesis introduces the first two stereogenic centres by a catalytic, asymmetric dihydroxylation, whereas the remaining two stereogenic centres are established by diastereoselective reactions. In this letter, we focus on the diastereoselectivity of these reactions and discuss the accessibility of cryptophycin unit A diastereomers.
Stichworte
products; cuprates; oxidations; addition reactions; diastereoselectivity; natural
Erscheinungsjahr
2008
Zeitschriftentitel
SYNLETT
Band
2008
Ausgabe
2
Seite(n)
273-277
ISSN
0936-5214
eISSN
1437-2096
Page URI
https://pub.uni-bielefeld.de/record/1592595

Zitieren

Eissler S, Neumann B, Stammler H-G, Sewald N. Synthetic routes towards cryptophycin unit A diastereomers. SYNLETT. 2008;2008(2):273-277.
Eissler, S., Neumann, B., Stammler, H. - G., & Sewald, N. (2008). Synthetic routes towards cryptophycin unit A diastereomers. SYNLETT, 2008(2), 273-277. doi:10.1055/s-2007-1000868
Eissler, S., Neumann, B., Stammler, H. - G., and Sewald, N. (2008). Synthetic routes towards cryptophycin unit A diastereomers. SYNLETT 2008, 273-277.
Eissler, S., et al., 2008. Synthetic routes towards cryptophycin unit A diastereomers. SYNLETT, 2008(2), p 273-277.
S. Eissler, et al., “Synthetic routes towards cryptophycin unit A diastereomers”, SYNLETT, vol. 2008, 2008, pp. 273-277.
Eissler, S., Neumann, B., Stammler, H.-G., Sewald, N.: Synthetic routes towards cryptophycin unit A diastereomers. SYNLETT. 2008, 273-277 (2008).
Eissler, Stefan, Neumann, Beate, Stammler, Hans-Georg, and Sewald, Norbert. “Synthetic routes towards cryptophycin unit A diastereomers”. SYNLETT 2008.2 (2008): 273-277.