N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine
Venugopal A, Willner A, Mitzel NW (2008)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 63(3): 339-341.
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Autor*in
Venugopal, Ajay;
Willner, Alexander;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The reaction of N,O-bis(trimethylsilyl)hydroxylamine with potassium hydride in pentane affords a product of the formula {K-6[OSiMe3](4)[ON(SiMe3)(2)](2)}, resulting from deprotonation followed by N-O bond cleavage and 1,2-silyl-shift. The compound was characterised by elemental analysis and by single crystal X-ray diffraction. The aggregate consists of a K3O3 bis-cubane core, with N(SiMe3)(2) groups at the oxygen atoms shared by the two cubes, and Me3Si groups attached to the four O vertices. Two weak K center dot center dot center dot N interactions are also detected in the solid state structure.
Stichworte
potassium;
aggregate;
bond cleavage;
crystal structure;
hydroxylamine
Erscheinungsjahr
2008
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
63
Ausgabe
3
Seite(n)
339-341
ISSN
0932-0776
Page URI
https://pub.uni-bielefeld.de/record/1592132
Zitieren
Venugopal A, Willner A, Mitzel NW. N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2008;63(3):339-341.
Venugopal, A., Willner, A., & Mitzel, N. W. (2008). N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 63(3), 339-341. https://doi.org/10.1515/znb-2008-0319
Venugopal, Ajay, Willner, Alexander, and Mitzel, Norbert W. 2008. “N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 63 (3): 339-341.
Venugopal, A., Willner, A., and Mitzel, N. W. (2008). N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 63, 339-341.
Venugopal, A., Willner, A., & Mitzel, N.W., 2008. N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 63(3), p 339-341.
A. Venugopal, A. Willner, and N.W. Mitzel, “N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 63, 2008, pp. 339-341.
Venugopal, A., Willner, A., Mitzel, N.W.: N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 63, 339-341 (2008).
Venugopal, Ajay, Willner, Alexander, and Mitzel, Norbert W. “N-O bond cleavage during the deprotonation of N,O-bis(trimethylsilyl)hydroxylamine”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 63.3 (2008): 339-341.
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