Syntheses and structures of (N ',N '-dimethylhydrazido)silanes

Gronde I, Neumann B, Willner A, Pape T, Mitzel NW (2009)
DALTON TRANSACTIONS (27): 5300-5309.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Gronde, Ingo; Neumann, BeateUniBi; Willner, Alexander; Pape, Tania; Mitzel, Norbert W.UniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
The hydrazidosilanes Ph2Si(NHNMe2)(2) (1), Me2Si(NHNMe2)(2) (2), PhSi(NHNMe2)(3) (3), MeSi(NHNMe2)(3) (4), PhClSi(NHNMe2)(2) (5), MeClSi(NHNMe2)(2) (6), Me2ClSi(NHNMe2) (7), MeClHSi(NHNMe2) (8), MeHSi(NHNMe2)(2) (9), Me2HSi(NHNMe2) (10), Me2NN[HSi(NHNMe2)(2)](2) (11) and Si(NHNMe2)(4) (12) have been prepared by the reaction of the corresponding chlorosilanes with N,N-dimethylhydrazine. Some of the compounds containing Si-Cl and N-H functions simultaneously (6, 7, 8) are very reactive and tend to polymerise and could only be characterised by spectroscopic methods (H-1, C-13, Si-29 NMR, IR, MS). All other compounds could additionally be characterised by elemental analyses. The structures of 1, 2, 5, 9, 11 and 12 in the solid state were determined by X-ray diffraction. These include the first structural determinations of compounds containing SiH-NH-N (9, 11) and SiCl-NH-N (5) units.
Erscheinungsjahr
2009
Zeitschriftentitel
DALTON TRANSACTIONS
Ausgabe
27
Seite(n)
5300-5309
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1591909

Zitieren

Gronde I, Neumann B, Willner A, Pape T, Mitzel NW. Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS. 2009;(27):5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., & Mitzel, N. W. (2009). Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS(27), 5300-5309. https://doi.org/10.1039/b900293f
Gronde, Ingo, Neumann, Beate, Willner, Alexander, Pape, Tania, and Mitzel, Norbert W. 2009. “Syntheses and structures of (N ',N '-dimethylhydrazido)silanes”. DALTON TRANSACTIONS, no. 27: 5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., and Mitzel, N. W. (2009). Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS, 5300-5309.
Gronde, I., et al., 2009. Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS, (27), p 5300-5309.
I. Gronde, et al., “Syntheses and structures of (N ',N '-dimethylhydrazido)silanes”, DALTON TRANSACTIONS, 2009, pp. 5300-5309.
Gronde, I., Neumann, B., Willner, A., Pape, T., Mitzel, N.W.: Syntheses and structures of (N ',N '-dimethylhydrazido)silanes. DALTON TRANSACTIONS. 5300-5309 (2009).
Gronde, Ingo, Neumann, Beate, Willner, Alexander, Pape, Tania, and Mitzel, Norbert W. “Syntheses and structures of (N ',N '-dimethylhydrazido)silanes”. DALTON TRANSACTIONS 27 (2009): 5300-5309.

55 References

Daten bereitgestellt von Europe PubMed Central.


Rakhlin, Dokl. Chem. (Engl.) 388(), 2003

Rakhlin, Dokl. Akad. Nauk SSSR 388(), 2003

Fessenden, Chem. Rev. 61(), 1961

Wannagat, Z. Anorg. Allg. Chem. 297(), 1958

Höfler, Monatsh. Chem. 97(), 1966

Wannagat, Z. Anorg. Allg. Chem. 299(), 1959

Wannagat, Monatsh. Chem. 97(), 1966

Wannagat, Z. Anorg. Allg. Chem. 310(), 1961

Witke, J. Organomet. Chem. 15(), 1968

Wiberg, Angew. Chem. 80(), 1968

Aylett, J. Inorg. Nucl. Chem. 2(), 1956

Glidewell, J. Chem. Soc. A (), 1970

Clegg, Z. Naturforsch. 34B(), 1979

Clegg, Chem. Ber. 116(), 1983

Mitzel, Organometallics 12(), 1993

Mitzel, Chem. Ber. 126(), 1993
Synthesis of Volatile Cyclic Silylamines and the Molecular Structures of Two 1-Aza-2,5-disilacyclopentane Derivatives.
Mitzel NW, Schmidbaur H, Rankin DW, Smart BA, Hofmann M, Schleyer PR., Inorg Chem 36(20), 1997
PMID: 11670093

Mitzel, Inorg. Chem. 34(), 1995

Mitzel, Chem.–Eur. J. 4(), 1998

Vojinović, Chem.–Eur. J. 10(), 2004

Mitzel, J. Chem. Soc., Dalton Trans. (), 1996

Niederprüm, Z. Anorg. Allg. Chem. 311(), 1961

Sergeeva, J. Allg. Chem. 30(), 1960

Kriegsmann, Z. Anorg. Allg. Chem. 310(), 1961

Jarvie, J. Chem. Soc. (), 1963

Sergeeva, Russ. J. Gen. Chem. 33(), 1963

Mitzel, J. Am. Chem. Soc. 119(), 1997

Mitzel, Angew. Chem., Int. Ed. Engl. 36(), 1997

Mitzel, J. Am. Chem. Soc. 120(), 1998

Losehand, Inorg. Chem. 37(), 1998

Mitzel, Eur. J. Inorg. Chem. (), 1998

Mitzel, Inorg. Chem. 38(), 1999

Mitzel, J. Chem. Soc., Dalton Trans. (), 1999

Losehand, J. Chem. Soc., Dalton Trans. (), 2000
SiONB unit as reference for blocked Si...N interactions in SiON compounds.
Mitzel NW, Losehand U, Bauer B., Inorg Chem 39(9), 2000
PMID: 11428121

Mitzel, Z. Naturforsch. 56b(), 2001

Vojinović, Z. Naturforsch. 59b(), 2004

Woski, Dalton Trans. (), 2008

Mitzel, J. Chem. Soc., Dalton Trans. (), 2002
Synthesis, decomposition, and structural studies in the gas phase and solid state of N,N-dimethylaminoxygermane.
Mitzel NW, Losehand U, Hinchley SL, Rankin DW., Inorg Chem 40(4), 2001
PMID: 11225108

Mitzel, J. Am. Chem. Soc. 112(), 2000
Three-membered ring or open chain molecule - (F3C)F2SiONMe2 a model for the alpha-effect in silicon chemistry.
Mitzel NW, Vojinovic K, Frohlich R, Foerster T, Robertson HE, Borisenko KB, Rankin DW., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190736

Gellermann, Z. Anorg. Allg. Chem. 627(), 2001

Dielkus, Organometallics 13(), 1994

Bode, J. Organomet. Chem. 482(), 1994

Klingebiel, Chem. Ber. 111(), 1978

Mitzel, Z. Naturforsch. 58B(), 2003

Airey, J. Mol. Struct. 8(), 1971

Wannagat, Z. Anorg. Allg. Chem. 572(), 1989

Mitzel, Z. Naturforsch. 58b(), 2003

Gibson, Inorg. Chem. 2(), 1963

Gillespie, Adv. Mol. Struct. Res. 4(), 1998

Heard, J. Mol. Struct. 237(), 2000

Gillespie, Coord. Chem. Rev. 51(), 2000

Farrugia, J. Appl. Crystallogr. 30(), 1997
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 19565082
PubMed | Europe PMC

Suchen in

Google Scholar