Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes

Venugopal A, Pape T, Willner A, Mitzel NW (2009)
DALTON TRANSACTIONS (29): 5715-5719.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Salt metathesis reactions involving the anhydrous rare-earth metal trichlorides MCl3 (M = Y, Ho, Er and Lu) and the N, N-diethylhydroxylaminato potassium salt, KONEt2 (1), and KC5Me5 result in formation of rare-earth metal hydroxylaminato complexes of the type [(C5Me5) M(mu-eta(1):eta(2)-ONEt2)-(eta(2)-ONEt2)](2) (M = Y (2a), Ho (2b), Er (2c) and Lu (2d)). Compound 1 was characterised by elemental analysis, compounds 2a and 2d by NMR spectroscopy and compounds 2a-d by elemental analyses, mass-spectrometry and single crystal X-ray diffraction. Compounds 2a-d are isostructural in the solid state. Effective saturation of the coordination sphere of the rare-earth metal atoms by the hydroxylaminato groups is achieved by the formation of three-membered MON rings.
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DALTON TRANSACTIONS
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29
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5715-5719
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Venugopal A, Pape T, Willner A, Mitzel NW. Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes. DALTON TRANSACTIONS. 2009;(29):5715-5719.
Venugopal, A., Pape, T., Willner, A., & Mitzel, N. W. (2009). Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes. DALTON TRANSACTIONS(29), 5715-5719. doi:10.1039/b904538d
Venugopal, A., Pape, T., Willner, A., and Mitzel, N. W. (2009). Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes. DALTON TRANSACTIONS, 5715-5719.
Venugopal, A., et al., 2009. Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes. DALTON TRANSACTIONS, (29), p 5715-5719.
A. Venugopal, et al., “Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes”, DALTON TRANSACTIONS, 2009, pp. 5715-5719.
Venugopal, A., Pape, T., Willner, A., Mitzel, N.W.: Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes. DALTON TRANSACTIONS. 5715-5719 (2009).
Venugopal, Ajay, Pape, Tania, Willner, Alexander, and Mitzel, Norbert W. “Bis(hydroxylaminato)-mono(pentamethylcyclopentadienyl) rare-earth metal complexes”. DALTON TRANSACTIONS 29 (2009): 5715-5719.

1 Zitation in Europe PMC

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Structural variations and molecular dynamics of rare-earth metal complexes with the N,N-bis(2-{pyrid-2-yl}ethyl)hydroxylaminato ligand.
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
PMID: 19774565

28 References

Daten bereitgestellt von Europe PubMed Central.


Kagan, Chem. Rev. 102(), 2002

Evans, Chem. Commun. (), 2001

Venugopal, Dalton Trans. (), 2007

Venugopal, Dalton Trans. (), 2008
Potassium hydroxylamine complexes.
Venugopal A, Berger RJ, Willner A, Pape T, Mitzel NW., Inorg Chem 47(11), 2008
PMID: 18461926

Venugopal, Z. Naturforsch. 63b(), 2008

Diedrich, Organometallics 19(), 2000

Armstrong, J. Organomet. Chem. 550(), 1998
Reactions of d0 group 4 amides with dioxygen. Preparation of unusual oxo aminoxy complexes and theoretical studies of their formation.
Wang R, Zhang XH, Chen SJ, Yu X, Wang CS, Beach DB, Wu YD, Xue ZL., J. Am. Chem. Soc. 127(14), 2005
PMID: 15810856

Dove, Chem. Commun. (), 2005

Mitzel, J. Chem. Soc. Dalton Trans. (), 1996

Wieghardt, Z. Anorg. Allg. Chem. 490(), 1982

Jana, Organometallics 27(), 2008

Jana, Chem. Commun. (), 2006

Ullrich, Eur. J. Inorg. Chem. (), 2006

Mitzel, Dalton Trans. (), 2004

Hausen, J. Organomet. Chem. 153(), 1978

Bösing, Dalton Trans. (), 2008

Lustig, Angew. Chem. 113(), 2001

Mitzel, Organometallics 18(), 1999

Willner, Dalton Trans. (), 2009

Dove, Organometallics 28(), 2009

Mahanthappa, Organometallics 23(), 2004

Mahanthappa, Chem. Commun (), 2002

Chesman, Dalton Trans. (), 2007

Evans, Organometallics 12(), 1993

Tonzetich, Inorg. Chim. Acta 345(), 2003

Manriquez, Inorg. Synth. 21(), 1982

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