A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer
Hagemann M, Pape T, Mitzel NW (2009)
ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64(3): 343-346.
Zeitschriftenaufsatz
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Autor*in
Hagemann, Michael;
Pape, Tania;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The reaction of lithium 2-(dimethylamino)ethanolate with Me2SiCl2 yielded a lithium chloride adduct of Me2Si-(OCH2CH2NMe2)(2). Despite the application of an excess of Me2SiCl2, the formation of ClMe2SiOCH2CH2NMe2 was not observed. [Me2Si(OCH2CH2NMe2)(2)center dot Li2Cl2] was characterised by NMR spectroscopy and determination of its crystal structure by X-ray diffraction. In the solid state it forms endless chains consisting of (2)center dot Li2Cl2 rhombi, with the lithium atoms chelated by the O and N atom of one OCH2CH2NMe2 substituent of Me2Si(OCH2CH2NMe2)(2) units.
Stichworte
N;
Aggregate;
Silicon;
Lithium;
O-Ligands;
Crystal Structure
Erscheinungsjahr
2009
Zeitschriftentitel
ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
64
Ausgabe
3
Seite(n)
343-346
ISSN
0932-0776
eISSN
1865-7117
Page URI
https://pub.uni-bielefeld.de/record/1591245
Zitieren
Hagemann M, Pape T, Mitzel NW. A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2009;64(3):343-346.
Hagemann, M., Pape, T., & Mitzel, N. W. (2009). A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(3), 343-346. https://doi.org/10.1515/znb-2009-0317
Hagemann, Michael, Pape, Tania, and Mitzel, Norbert W. 2009. “A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer”. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64 (3): 343-346.
Hagemann, M., Pape, T., and Mitzel, N. W. (2009). A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64, 343-346.
Hagemann, M., Pape, T., & Mitzel, N.W., 2009. A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(3), p 343-346.
M. Hagemann, T. Pape, and N.W. Mitzel, “A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer”, ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 64, 2009, pp. 343-346.
Hagemann, M., Pape, T., Mitzel, N.W.: A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 64, 343-346 (2009).
Hagemann, Michael, Pape, Tania, and Mitzel, Norbert W. “A Coordination Polymer of Bis-[2-(dimethylamino)ethanolato]dimethylsilane with a Lithium Chloride Dimer”. ZEITSCHRIFT FUER NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64.3 (2009): 343-346.
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