Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes
Boesing P, Stammler H-G, Mitzel NW (2009)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64(10): 1208-1212.
Zeitschriftenaufsatz
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Autor*in
Boesing, Patrick;
Stammler, Hans-GeorgUniBi;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The reduction of a partially deprotonated bishydroxylamine complex {((Bu2Ga)-Bu-t)(2)[cyclo-ON(Me)(CH2)(2)-(Me)NO][HON(Me)(CH2)(2)(Me)(H)NO ]} with a reagent composed of titanium tetrachloride and methyllithium leads to the reduction of one of the N-O groups to an amine function affording the salt {(Bu-t(2))Ga)[cyclo-ON(H)(Me)(CH2)(2)NHMe]}(+) {tBu(2))GaCl2}(-). This has been characterised by H-1 and C-13 NMR spectroscopy, by elemental analysis and by single crystal X-ray diffraction, showing the neutral amine/hydroxylamine ligand to be present in its tautomeric aminoxide form. The molecules form hexameric cyclic aggregates by N-H center dot center dot center dot Cl hydrogen bonds.
Stichworte
Crystal Structure;
N;
Aminoxide;
O-Ligands;
Hydroxylamine;
Gallium
Erscheinungsjahr
2009
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
64
Ausgabe
10
Seite(n)
1208-1212
ISSN
0932-0776
eISSN
1865-7117
Page URI
https://pub.uni-bielefeld.de/record/1589756
Zitieren
Boesing P, Stammler H-G, Mitzel NW. Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2009;64(10):1208-1212.
Boesing, P., Stammler, H. - G., & Mitzel, N. W. (2009). Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(10), 1208-1212. https://doi.org/10.1515/znb-2009-1015
Boesing, Patrick, Stammler, Hans-Georg, and Mitzel, Norbert W. 2009. “Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64 (10): 1208-1212.
Boesing, P., Stammler, H. - G., and Mitzel, N. W. (2009). Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64, 1208-1212.
Boesing, P., Stammler, H.-G., & Mitzel, N.W., 2009. Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 64(10), p 1208-1212.
P. Boesing, H.-G. Stammler, and N.W. Mitzel, “Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 64, 2009, pp. 1208-1212.
Boesing, P., Stammler, H.-G., Mitzel, N.W.: Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 64, 1208-1212 (2009).
Boesing, Patrick, Stammler, Hans-Georg, and Mitzel, Norbert W. “Partial Reduction of the N-O Functions of Partially Deprotonated Bis(hydroxylamine) Complexes”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 64.10 (2009): 1208-1212.
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