Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids

Alter C, Neumann B, Stammler H-G, Hoge B (2018)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (7): 867-875.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
Facile replacement of the p-fluorine atom in bis(diethylamino)pentafluorophenylphosphane [(Et2N)(2)PC6F5] by organolithium derivatives LiR (R = CH3, n-Bu, Ph), lithium alkoxides (R = OMe, OEt) and amides (NMe2, NEt2) is described. The obtained phosphanes p-R-C6F4-P(NEt2)(2) are fully characterized. Their acid-catalyzed hydrolysis affords the corresponding phosphinic acids p-R-C6F4-P(O)(H)OH, which are smoothly oxidized by treatment with a mixture of DMSO/I-2 to phosphonic acids p-R-C6F4-P(O)(OH)(2).
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Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Zeitschriftennummer
7
Seite
867-875
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Alter C, Neumann B, Stammler H-G, Hoge B. Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018;(7):867-875.
Alter, C., Neumann, B., Stammler, H. - G., & Hoge, B. (2018). Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(7), 867-875. doi:10.1002/ejic.201701402
Alter, C., Neumann, B., Stammler, H. - G., and Hoge, B. (2018). Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 867-875.
Alter, C., et al., 2018. Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (7), p 867-875.
C. Alter, et al., “Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, pp. 867-875.
Alter, C., Neumann, B., Stammler, H.-G., Hoge, B.: Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 867-875 (2018).
Alter, Christian, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 7 (2018): 867-875.