Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite

Lindner R, Rahe P, Kittelmann M, Gourdon A, Bechstein R, Kühnle A (2014)
Angewandte Chemie. International Edition 53(30): 7952-7955.

Download
No fulltext has been uploaded. References only!
Journal Article | Original Article | Published | English

No fulltext has been uploaded

Author
; ; ; ; ;
Abstract
A substrate-guided photochemical reaction of C-60 fullerenes on calcite, a bulk insulator, investigated by non-contact atomic force microscopy is presented. The success of the covalent linkage is evident from a shortening of the intermolecular distances, which is clearly expressed by the disappearance of the moire pattern. Furthermore, UV/Vis spectroscopy and mass spectrometry measurements carried out on thick films demonstrate the ability of our setup for initiating the photoinduced reaction. The irradiation of C-60 results in well-oriented covalently linked domains. The orientation of these domains is dictated by the lattice dimensions of the underlying calcite substrate. Using the lattice mismatch to deliberately steer the direction of the chemical reaction is expected to constitute a general design principle for on-surface synthesis. This work thus provides a strategy for controlled fabrication of oriented, covalent networks on bulk insulators.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Lindner R, Rahe P, Kittelmann M, Gourdon A, Bechstein R, Kühnle A. Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition. 2014;53(30):7952-7955.
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., & Kühnle, A. (2014). Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition, 53(30), 7952-7955. doi:10.1002/anie.201309128
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., and Kühnle, A. (2014). Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition 53, 7952-7955.
Lindner, R., et al., 2014. Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition, 53(30), p 7952-7955.
R. Lindner, et al., “Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite”, Angewandte Chemie. International Edition, vol. 53, 2014, pp. 7952-7955.
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., Kühnle, A.: Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition. 53, 7952-7955 (2014).
Lindner, Robert, Rahe, Philipp, Kittelmann, Markus, Gourdon, Andre, Bechstein, Ralf, and Kühnle, Angelika. “Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite”. Angewandte Chemie. International Edition 53.30 (2014): 7952-7955.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Sources

PMID: 24692299
PubMed | Europe PMC

Search this title in

Google Scholar