Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation

Bader J, Maier AFG, Paradies J, Hoge B (2017)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (24): 3053-3056.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Transfer hydrogenation plays an important part in organic chemistry. Recently, strong Lewis acids like B(C6F5)(3) have been introduced as a catalyst for these reactions. We successfully employed the Lewis acid (C2F5)(3)PF2 as a catalyst in the transfer hydrogenation between 1,3,5-trimethylcyclohexa-1,4-diene and 1,1-diphenylethylene. Surprisingly, the treatment of the diene alone with a catalytic amount of (C2F5)(3)PF2 led to a quantitative dismutation to mesitylene and 1,3,5-trimethylcyclohexane. With B(C6F5)(3), there was a solvent-dependency: in CH2Cl2 mainly the dismutation products were obtained, while in toluene the evolution of H-2 was observed. Additionally, the catalytic activity of various perfluoroalkylated germanes and silanes was tested.
Erscheinungsjahr
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Zeitschriftennummer
24
Seite
3053-3056
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Bader J, Maier AFG, Paradies J, Hoge B. Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2017;(24):3053-3056.
Bader, J., Maier, A. F. G., Paradies, J., & Hoge, B. (2017). Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(24), 3053-3056. doi:10.1002/ejic.201700524
Bader, J., Maier, A. F. G., Paradies, J., and Hoge, B. (2017). Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 3053-3056.
Bader, J., et al., 2017. Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (24), p 3053-3056.
J. Bader, et al., “Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, pp. 3053-3056.
Bader, J., Maier, A.F.G., Paradies, J., Hoge, B.: Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 3053-3056 (2017).
Bader, Julia, Maier, Alexander F. G., Paradies, Jan, and Hoge, Berthold. “Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 24 (2017): 3053-3056.