Tris(perfluorotolyl)borane-A Boron Lewis Superacid

Körte LA, Schwabedissen J, Soffner M, Blomeyer S, Reuter C, Vishnevskiy Y, Neumann B, Stammler H-G, Mitzel NW (2017)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56(29): 8578-8582.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
Tris[tetrafluoro-4-(trifluoromethyl)phenyl] borane (BTolF) was prepared by treating boron tribromide with tetrameric F3CC6F4-Cu-I. The F3CC6F4-CuI was generated from F3CC6F4MgBr and copper(I) bromide. Lewis acidities of BTolF evaluated by the Gutmann-Beckett method and calculated fluoride-ion affinities are 9 and 10%, respectively, higher than that of tris(pentafluorophenyl) borane (BCF) and even higher than that of SbF5. The molecular structures of BTolF and BCF were determined by gas-phase electron diffraction, that of BTolF also by single-crystal X-ray diffraction.
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Zeitschriftentitel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Band
56
Zeitschriftennummer
29
Seite
8578-8582
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eISSN
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Körte LA, Schwabedissen J, Soffner M, et al. Tris(perfluorotolyl)borane-A Boron Lewis Superacid. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2017;56(29):8578-8582.
Körte, L. A., Schwabedissen, J., Soffner, M., Blomeyer, S., Reuter, C., Vishnevskiy, Y., Neumann, B., et al. (2017). Tris(perfluorotolyl)borane-A Boron Lewis Superacid. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56(29), 8578-8582. doi:10.1002/anie.201704097
Körte, L. A., Schwabedissen, J., Soffner, M., Blomeyer, S., Reuter, C., Vishnevskiy, Y., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2017). Tris(perfluorotolyl)borane-A Boron Lewis Superacid. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56, 8578-8582.
Körte, L.A., et al., 2017. Tris(perfluorotolyl)borane-A Boron Lewis Superacid. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56(29), p 8578-8582.
L.A. Körte, et al., “Tris(perfluorotolyl)borane-A Boron Lewis Superacid”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 56, 2017, pp. 8578-8582.
Körte, L.A., Schwabedissen, J., Soffner, M., Blomeyer, S., Reuter, C., Vishnevskiy, Y., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Tris(perfluorotolyl)borane-A Boron Lewis Superacid. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 56, 8578-8582 (2017).
Körte, Leif Arne, Schwabedissen, Jan, Soffner, Marcel, Blomeyer, Sebastian, Reuter, Christian, Vishnevskiy, Yury, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Tris(perfluorotolyl)borane-A Boron Lewis Superacid”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.29 (2017): 8578-8582.

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Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid.
Maskey R, Schädler M, Legler C, Greb L., Angew Chem Int Ed Engl 57(6), 2018
PMID: 29240282

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