Facile routes to abnormal-NHC-cobalt(II) complexes

Ghadwal R, Lamm J-H, Rottschäfer D, Schuermann CJ, Demeshko S (2017)
DALTON TRANSACTIONS 46(24): 7664-7667.

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Abstract
Deprotonation of [IPrPh]I (1) with Co{N(SiMe3)(2)}(2) readily affords the abnormal N-heterocyclic carbene (aNHC) complex (aIPr(Ph))(2)CoI2 (2) (aIPr(Ph) = 1,3-bis(2,6-iPr(2)C(6)H(3))-2-phenyl-imidazol4-ylidene). Treatment of 1 with NaHBEt3 yields (aIPr(Ph)) BEt3 (3) that serves as an aNHC-transfer agent and yields (aIPr(Ph)) Co{N(SiMe3)(2)}(2) (4) on reaction with Co{N(SiMe3)(2)}(2).
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Ghadwal R, Lamm J-H, Rottschäfer D, Schuermann CJ, Demeshko S. Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS. 2017;46(24):7664-7667.
Ghadwal, R., Lamm, J. - H., Rottschäfer, D., Schuermann, C. J., & Demeshko, S. (2017). Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS, 46(24), 7664-7667. doi:10.1039/c7dt01778b
Ghadwal, R., Lamm, J. - H., Rottschäfer, D., Schuermann, C. J., and Demeshko, S. (2017). Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS 46, 7664-7667.
Ghadwal, R., et al., 2017. Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS, 46(24), p 7664-7667.
R. Ghadwal, et al., “Facile routes to abnormal-NHC-cobalt(II) complexes”, DALTON TRANSACTIONS, vol. 46, 2017, pp. 7664-7667.
Ghadwal, R., Lamm, J.-H., Rottschäfer, D., Schuermann, C.J., Demeshko, S.: Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS. 46, 7664-7667 (2017).
Ghadwal, Rajendra, Lamm, Jan-Hendrik, Rottschäfer, Dennis, Schuermann, Christian J., and Demeshko, Serhiy. “Facile routes to abnormal-NHC-cobalt(II) complexes”. DALTON TRANSACTIONS 46.24 (2017): 7664-7667.
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The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.
Rottschäfer D, Ebeler F, Strothmann T, Neumann B, Stammler HG, Mix A, Ghadwal RS., Chemistry 24(15), 2018
PMID: 29363830
Crystalline Radicals Derived from Classical N-Heterocyclic Carbenes.
Rottschäfer D, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS., Angew Chem Int Ed Engl (), 2018
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N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid.
Rottschäfer D, Neumann B, Stammler HG, Ghadwal RS., Chemistry 23(38), 2017
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Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes.
Ho NKT, Neumann B, Stammler HG, Menezes da Silva VH, Watanabe DG, Braga AAC, Ghadwal RS., Dalton Trans 46(36), 2017
PMID: 28853488

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