Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses

Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2017)
CHEMISTRY-A EUROPEAN JOURNAL 23(7): 1568-1575.

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Abstract
Commercially available BiPh3 was treated with perfluoroalkylphosphinic acids [for example, (C2F5)(2)P(O) OH] to generate novel, highly Lewis acidic bismuth(III) perfluoroalkylphosphinates of the type PhxBi[(R2PO2)-P-F](3-x) (x= 0, 1, 2) (R-F =-C2F5, -C-4 F-9). The first bismuth(V) perfluoroalkylphosphinate, Ph3Bi[(C2F5)(2)PO2](2), was synthesized from Ph3BiCl2 and Ag[(C2F5)(2)PO2]. Examples for the successful application of the catalytically active bismuth(III) and bismuth(V) phosphinates in carbon-carbon bond forming reactions, such as Friedel-Crafts acylation and alkylation, Diels-Alder, Strecker and Mannich reaction, are presented.
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Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses. CHEMISTRY-A EUROPEAN JOURNAL. 2017;23(7):1568-1575.
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2017). Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), 1568-1575. doi:10.1002/chem.201604914
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2017). Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses. CHEMISTRY-A EUROPEAN JOURNAL 23, 1568-1575.
Solyntjes, S., et al., 2017. Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), p 1568-1575.
S. Solyntjes, et al., “Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 23, 2017, pp. 1568-1575.
Solyntjes, S., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses. CHEMISTRY-A EUROPEAN JOURNAL. 23, 1568-1575 (2017).
Solyntjes, Sven, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses”. CHEMISTRY-A EUROPEAN JOURNAL 23.7 (2017): 1568-1575.
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