A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex

Dammers S, Zimmermann T, Walleck S, Stammler A, Bögge H, Bill E, Glaser T (2017)
INORGANIC CHEMISTRY 56(4): 1779-1782.

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Abstract
The reaction of the new dinucleating ligand susan(6-Me) with Fe(BF4)(2)6H(2)O results in formation of the homovalent (FeFeII)-Fe-II complex [(susan(6-Me)){Fe-II(-F)(2)Fe-II}](2+) and the mixed-valence (FeFeIII)-Fe-II complex [(susan(6-Me)){(FeF)-F-II(-F)(FeF)-F-III}](2+) depending on the absence or presence of dioxygen, respectively. Complex [(susan(6-Me)){(FeF)-F-II(-F)(FeF)-F-III}](2+) is the first molecular mixed-valence complex with a fluorido bridge. The short Fe-III-F bond of 1.87 a causes a large reorganization energy, resulting in a localized class II system with an intervalence charge-transfer band of high energy at 10000 cm(1).
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Dammers S, Zimmermann T, Walleck S, et al. A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex. INORGANIC CHEMISTRY. 2017;56(4):1779-1782.
Dammers, S., Zimmermann, T., Walleck, S., Stammler, A., Bögge, H., Bill, E., & Glaser, T. (2017). A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex. INORGANIC CHEMISTRY, 56(4), 1779-1782. doi:10.1021/acs.inorgchem.6b03093
Dammers, S., Zimmermann, T., Walleck, S., Stammler, A., Bögge, H., Bill, E., and Glaser, T. (2017). A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex. INORGANIC CHEMISTRY 56, 1779-1782.
Dammers, S., et al., 2017. A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex. INORGANIC CHEMISTRY, 56(4), p 1779-1782.
S. Dammers, et al., “A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex”, INORGANIC CHEMISTRY, vol. 56, 2017, pp. 1779-1782.
Dammers, S., Zimmermann, T., Walleck, S., Stammler, A., Bögge, H., Bill, E., Glaser, T.: A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex. INORGANIC CHEMISTRY. 56, 1779-1782 (2017).
Dammers, Susanne, Zimmermann, Thomas, Walleck, Stephan, Stammler, Anja, Bögge, Hartmut, Bill, Eckhard, and Glaser, Thorsten. “A Mixed-Valence Fluorido-Bridged (FeFeIII)-Fe-II Complex”. INORGANIC CHEMISTRY 56.4 (2017): 1779-1782.
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PMID: 28128935
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