Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety

Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B (2016)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55(52): 16161-16164.

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Journal Article | Original Article | Published | English

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Abstract
The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)(3)H at low temperatures. Subsequent quenching of the resulting salt-like compounds with suitable electrophiles, such as transition-metal complexes or Group14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)(3)] as a powerful nucleophilic transfer reagent.
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Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B. Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2016;55(52):16161-16164.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., & Hoge, B. (2016). Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), 16161-16164. doi:10.1002/anie.201609575
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., and Hoge, B. (2016). Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55, 16161-16164.
Schwarze, N., et al., 2016. Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), p 16161-16164.
N. Schwarze, et al., “Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 55, 2016, pp. 16161-16164.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H.-G., Hoge, B.: Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 55, 16161-16164 (2016).
Schwarze, Nico, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.52 (2016): 16161-16164.
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