Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts

Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2016)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016(25): 3999-4010.

Download
No fulltext has been uploaded. References only!
Journal Article | Original Article | Published | English

No fulltext has been uploaded

Abstract
Fluoride ion affinities (FIA), provided by DFT calculations, are exceedingly useful for the design of new Lewis acids with defined reactivities. Herein, we report the synthesis, characterization and reactivity of new difluoro(perfluoroorganyl) phosphoranes, which readily abstract fluoride ions from di-fluoro(triorganyl)phosphoranes. Highly reactive fluorobismuthonium cations and the [Ph3Bi(NCCH3)(2)](2+) cation are accessible through the treatment of difluoro(triorganyl) bismuth(V) compounds with the Lewis acidic phosphoranes discussed here.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2016;2016(25):3999-4010.
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2016). Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016(25), 3999-4010. doi:10.1002/ejic.201600539
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2016). Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016, 3999-4010.
Solyntjes, S., et al., 2016. Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016(25), p 3999-4010.
S. Solyntjes, et al., “Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2016, 2016, pp. 3999-4010.
Solyntjes, S., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2016, 3999-4010 (2016).
Solyntjes, Sven, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016.25 (2016): 3999-4010.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar