Synthesis of Bis(pentafluoroethyl)germanes

Pelzer S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2016)
Chemistry 22(14): 4758-4763.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
The chemistry of bis(pentafluoroethyl)germanes (C2F5)(2)GeX2 is presented. The synthesis of such species requires Br2GePh2, wherein the phenyl substituents function as suitable protecting groups. After treatment with two equivalents of LiC2F5, (C2F5)(2)GePh2 is produced. The replacement of the phenyl rings is smoothly effected by gaseous HBr or HCl in the presence of a Lewis acidic catalyst. The trigermoxane [(C2F5)(2)GeO](3) results from the reaction of (C2F5)(2)GeBr2 with Ag2CO3. Its crystalline 1,10-phenanthroline adduct was fully characterised by X-ray diffraction. The combination of (C2F5)(2)GeBr2 with Bu3SnH gave rise to the formation of (C2F5)(2)GeH2.
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Zeitschriftentitel
Chemistry
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22
Zeitschriftennummer
14
Seite
4758-4763
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Pelzer S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Synthesis of Bis(pentafluoroethyl)germanes. Chemistry. 2016;22(14):4758-4763.
Pelzer, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2016). Synthesis of Bis(pentafluoroethyl)germanes. Chemistry, 22(14), 4758-4763. doi:10.1002/chem.201505084
Pelzer, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2016). Synthesis of Bis(pentafluoroethyl)germanes. Chemistry 22, 4758-4763.
Pelzer, S., et al., 2016. Synthesis of Bis(pentafluoroethyl)germanes. Chemistry, 22(14), p 4758-4763.
S. Pelzer, et al., “Synthesis of Bis(pentafluoroethyl)germanes”, Chemistry, vol. 22, 2016, pp. 4758-4763.
Pelzer, S., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Synthesis of Bis(pentafluoroethyl)germanes. Chemistry. 22, 4758-4763 (2016).
Pelzer, Stefanie, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Synthesis of Bis(pentafluoroethyl)germanes”. Chemistry 22.14 (2016): 4758-4763.

3 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

The Bis(pentafluoroethyl)germylene Trimethylphosphane Adduct (C2 F5 )2 Ge⋅PMe3 : Characterization, Ligand Properties, and Reactivity.
Pelzer S, Neumann B, Stammler HG, Ignat'ev N, Hoge B., Angew Chem Int Ed Engl 55(20), 2016
PMID: 27060298
Hypervalent Pentafluoroethylgermanium Compounds, [(C2 F5 )n GeX5-n ]- and [(C2 F5 )3 GeF3 ]2- (X=F, Cl; n=2-5).
Pelzer S, Neumann B, Stammler HG, Ignat'ev N, Hoge B., Chemistry 22(46), 2016
PMID: 27539166

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