Deposition and self-assembly of large magnetic molecules

Donner J, Broschinski J-P, Glaser T, Wegner D (2015)
Journal of Physical Chemistry C 119(51): 28660-28665.

Journal Article | Published | English

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Abstract
We have used two different unconventional preparation techniques, namely, pulse injection and rapid heating, to deposit large trinuclear transition-metal complexes onto a Au(111) surface under ultrahigh-vacuum conditions. Both techniques turn out to provide a clean preparation and leave the molecules intact upon deposition. While pulse injection leads to isolated molecules on the surface, rapid heating yields close-packed ordered monolayer islands. From a comparison of topographies and electronic structures we conclude that both molecule-substrate and intermolecular interactions are relatively weak We discuss the reasons for the appearance of the different structures and give a detailed comparison of both deposition techniques which allows us to evaluate their specific advantages and drawbacks. Our results show that these relatively simple and cost-efficient preparation techniques are suitable for nanoscale studies of large molecules such as single-molecule magnets.
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Donner J, Broschinski J-P, Glaser T, Wegner D. Deposition and self-assembly of large magnetic molecules. Journal of Physical Chemistry C. 2015;119(51):28660-28665.
Donner, J., Broschinski, J. - P., Glaser, T., & Wegner, D. (2015). Deposition and self-assembly of large magnetic molecules. Journal of Physical Chemistry C, 119(51), 28660-28665.
Donner, J., Broschinski, J. - P., Glaser, T., and Wegner, D. (2015). Deposition and self-assembly of large magnetic molecules. Journal of Physical Chemistry C 119, 28660-28665.
Donner, J., et al., 2015. Deposition and self-assembly of large magnetic molecules. Journal of Physical Chemistry C, 119(51), p 28660-28665.
J. Donner, et al., “Deposition and self-assembly of large magnetic molecules”, Journal of Physical Chemistry C, vol. 119, 2015, pp. 28660-28665.
Donner, J., Broschinski, J.-P., Glaser, T., Wegner, D.: Deposition and self-assembly of large magnetic molecules. Journal of Physical Chemistry C. 119, 28660-28665 (2015).
Donner, Judith, Broschinski, Jan-Philipp, Glaser, Thorsten, and Wegner, Daniel. “Deposition and self-assembly of large magnetic molecules”. Journal of Physical Chemistry C 119.51 (2015): 28660-28665.
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