A Neutral Silicon/Phosphorus Frustrated Lewis Pair

Waerder B, Pieper M, Körte LA, Kinder TA, Mix A, Neumann B, Stammler H-G, Mitzel NW (2015)
Angewandte Chemie International Edition 54(45): 13416-13419.

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Abstract
Frustrated Lewis pairs (FLPs) have a great potential for activation of small molecules. Most known FLP systems are based on boron or aluminum atoms as acid functions, few on zinc, and only two on boron-isoelectronic silicenium cation systems. The first FLP system based on a neutral silane, (C2F5)(3)SiCH2P(tBu)(2) (1), was prepared from (C2F5)(3)SiCl with C2F5 groups of very high electronegativity and LiCH2P(tBu)(2). 1 is capable of cleaving hydrogen, and adds CO2 and SO2. Hydrogen splitting was confirmed by H/D scrambling reactions. The structures of 1, its CO2 and SO2 adducts, and a decomposition product with CO2 were elucidated by X-ray diffraction.
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Waerder B, Pieper M, Körte LA, et al. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 2015;54(45):13416-13419.
Waerder, B., Pieper, M., Körte, L. A., Kinder, T. A., Mix, A., Neumann, B., Stammler, H. - G., et al. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), 13416-13419. doi:10.1002/anie.201504171
Waerder, B., Pieper, M., Körte, L. A., Kinder, T. A., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition 54, 13416-13419.
Waerder, B., et al., 2015. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), p 13416-13419.
B. Waerder, et al., “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”, Angewandte Chemie International Edition, vol. 54, 2015, pp. 13416-13419.
Waerder, B., Pieper, M., Körte, L.A., Kinder, T.A., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 54, 13416-13419 (2015).
Waerder, Benedikt, Pieper, Martin, Körte, Leif Arne, Kinder, Timo A., Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”. Angewandte Chemie International Edition 54.45 (2015): 13416-13419.
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Imidazole-stabilized, electron-deficient boron cations.
Sato K, Tan TTY, Schafers F, Hahn FE, Stephan DW., Dalton Trans 46(47), 2017
PMID: 29138766
Reactivity of the geminal phosphinoborane tBu2PCH2BPh2 towards alkynes, nitriles, and nitrilium triflates.
Habraken ERM, Mens LC, Nieger M, Lutz M, Ehlers AW, Slootweg JC., Dalton Trans 46(36), 2017
PMID: 28880036
Silyl Chalconium Ions: Synthesis, Structure and Application in Hydrodefluorination Reactions.
Kordts N, Kunzler S, Rathjen S, Sieling T, Großekappenberg H, Schmidtmann M, Muller T., Chemistry 23(42), 2017
PMID: 28374465
Dihydrogen Splitting Using Dialkylsilylene-Based Frustrated Lewis Pairs.
Dong Z, Li Z, Liu X, Yan C, Wei N, Kira M, Muller T., Chem Asian J 12(11), 2017
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Nuclear spin hyperpolarization with ansa-aminoboranes: a metal-free perspective for parahydrogen-induced polarization.
Zhivonitko VV, Sorochkina K, Chernichenko K, Kotai B, Foldes T, Papai I, Telkki VV, Repo T, Koptyug I., Phys Chem Chem Phys 18(40), 2016
PMID: 27711602
Intramolecular cooperativity in frustrated Lewis pairs.
Korte LA, Blomeyer S, Heidemeyer S, Mix A, Neumann B, Mitzel NW., Chem. Commun. (Camb.) 52(64), 2016
PMID: 27440500
Novel B(Ar')2(Ar'') hetero-tri(aryl)boranes: a systematic study of Lewis acidity.
Blagg RJ, Simmons TR, Hatton GR, Courtney JM, Bennett EL, Lawrence EJ, Wildgoose GG., Dalton Trans 45(14), 2016
PMID: 26541517

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