A Neutral Silicon/Phosphorus Frustrated Lewis Pair

Waerder B, Pieper M, Körte LA, Kinder TA, Mix A, Neumann B, Stammler H-G, Mitzel NW (2015)
Angewandte Chemie International Edition 54(45): 13416-13419.

Journal Article | Published | English

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Abstract
Frustrated Lewis pairs (FLPs) have a great potential for activation of small molecules. Most known FLP systems are based on boron or aluminum atoms as acid functions, few on zinc, and only two on boron-isoelectronic silicenium cation systems. The first FLP system based on a neutral silane, (C2F5)(3)SiCH2P(tBu)(2) (1), was prepared from (C2F5)(3)SiCl with C2F5 groups of very high electronegativity and LiCH2P(tBu)(2). 1 is capable of cleaving hydrogen, and adds CO2 and SO2. Hydrogen splitting was confirmed by H/D scrambling reactions. The structures of 1, its CO2 and SO2 adducts, and a decomposition product with CO2 were elucidated by X-ray diffraction.
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Waerder B, Pieper M, Körte LA, et al. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 2015;54(45):13416-13419.
Waerder, B., Pieper, M., Körte, L. A., Kinder, T. A., Mix, A., Neumann, B., Stammler, H. - G., et al. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), 13416-13419.
Waerder, B., Pieper, M., Körte, L. A., Kinder, T. A., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition 54, 13416-13419.
Waerder, B., et al., 2015. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), p 13416-13419.
B. Waerder, et al., “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”, Angewandte Chemie International Edition, vol. 54, 2015, pp. 13416-13419.
Waerder, B., Pieper, M., Körte, L.A., Kinder, T.A., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 54, 13416-13419 (2015).
Waerder, Benedikt, Pieper, Martin, Körte, Leif Arne, Kinder, Timo A., Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”. Angewandte Chemie International Edition 54.45 (2015): 13416-13419.
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PMID: 26423202
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