The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role

Bandeira NAG, Garai S, Müller A, Bo C (2015)
Chemical Communications 51(85): 15596-15599.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network of hydrogen bonds across the water layers in the first metal coordination sphere facilitates the proton abstraction and nucleophilic addition of water. The highly acidic properties of the polyoxometalate cluster are crucial for explaining the catalysed hydration.
Erscheinungsjahr
Zeitschriftentitel
Chemical Communications
Band
51
Zeitschriftennummer
85
Seite
15596-15599
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Bandeira NAG, Garai S, Müller A, Bo C. The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications. 2015;51(85):15596-15599.
Bandeira, N. A. G., Garai, S., Müller, A., & Bo, C. (2015). The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications, 51(85), 15596-15599. doi:10.1039/c5cc06423f
Bandeira, N. A. G., Garai, S., Müller, A., and Bo, C. (2015). The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications 51, 15596-15599.
Bandeira, N.A.G., et al., 2015. The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications, 51(85), p 15596-15599.
N.A.G. Bandeira, et al., “The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role”, Chemical Communications, vol. 51, 2015, pp. 15596-15599.
Bandeira, N.A.G., Garai, S., Müller, A., Bo, C.: The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role. Chemical Communications. 51, 15596-15599 (2015).
Bandeira, Nuno A. G., Garai, Somenath, Müller, Achim, and Bo, Carles. “The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role”. Chemical Communications 51.85 (2015): 15596-15599.

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Anions coordinating anions: analysis of the interaction between anionic Keplerate nanocapsules and their anionic ligands.
Melgar D, Bandeira NA, Bonet Avalos J, Bo C., Phys Chem Chem Phys 19(7), 2017
PMID: 28155941

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