UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]

Chrostowska A, Dargelos A, Baylère P, Darrigan C, Weber L, Halama J (2015)
European Journal of Inorganic Chemistry 2015(31): 5196-5201.

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Abstract
Flash vacuum thermolysis of N,N′-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaborole (1) and N,N′-di-tert-butyl-2-cyano-2,3-dihydro-1H-1,3,2-diazaborole (2) has been performed with a progressive increase in temperature and direct analysis of the gaseous flow by UV-photoelectron spectroscopy. The generation of isobutene was confirmed by its PE bands, and the formation of 2,3-dihydro-1H-1,3,2-diazaborole (1′) and 2-cyano-2,3-dihydro-1H-1,3,2-diazaborole (2′) has also been evidenced. These experimental results have been corroborated by TDDFT and OVGF calculations of the ionization energies.
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Chrostowska A, Dargelos A, Baylère P, Darrigan C, Weber L, Halama J. UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry. 2015;2015(31):5196-5201.
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., & Halama, J. (2015). UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry, 2015(31), 5196-5201.
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., and Halama, J. (2015). UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry 2015, 5196-5201.
Chrostowska, A., et al., 2015. UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry, 2015(31), p 5196-5201.
A. Chrostowska, et al., “UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]”, European Journal of Inorganic Chemistry, vol. 2015, 2015, pp. 5196-5201.
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., Halama, J.: UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry. 2015, 5196-5201 (2015).
Chrostowska, Anna, Dargelos, Alain, Baylère, Patrick, Darrigan, Clovis, Weber, Lothar, and Halama, Johannes. “UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]”. European Journal of Inorganic Chemistry 2015.31 (2015): 5196-5201.
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