UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]

Chrostowska A, Dargelos A, Baylère P, Darrigan C, Weber L, Halama J (2015)
European Journal of Inorganic Chemistry 2015(31): 5196-5201.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Flash vacuum thermolysis of N,N′-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaborole (1) and N,N′-di-tert-butyl-2-cyano-2,3-dihydro-1H-1,3,2-diazaborole (2) has been performed with a progressive increase in temperature and direct analysis of the gaseous flow by UV-photoelectron spectroscopy. The generation of isobutene was confirmed by its PE bands, and the formation of 2,3-dihydro-1H-1,3,2-diazaborole (1′) and 2-cyano-2,3-dihydro-1H-1,3,2-diazaborole (2′) has also been evidenced. These experimental results have been corroborated by TDDFT and OVGF calculations of the ionization energies.
Erscheinungsjahr
Zeitschriftentitel
European Journal of Inorganic Chemistry
Band
2015
Zeitschriftennummer
31
Seite
5196-5201
ISSN
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Chrostowska A, Dargelos A, Baylère P, Darrigan C, Weber L, Halama J. UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry. 2015;2015(31):5196-5201.
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., & Halama, J. (2015). UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry, 2015(31), 5196-5201. doi:10.1002/ejic.201500967
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., and Halama, J. (2015). UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry 2015, 5196-5201.
Chrostowska, A., et al., 2015. UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry, 2015(31), p 5196-5201.
A. Chrostowska, et al., “UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]”, European Journal of Inorganic Chemistry, vol. 2015, 2015, pp. 5196-5201.
Chrostowska, A., Dargelos, A., Baylère, P., Darrigan, C., Weber, L., Halama, J.: UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]. European Journal of Inorganic Chemistry. 2015, 5196-5201 (2015).
Chrostowska, Anna, Dargelos, Alain, Baylère, Patrick, Darrigan, Clovis, Weber, Lothar, and Halama, Johannes. “UV-Photoelectron Spectroscopic Studies of the Simplest 2,3-Dihydro-1H-1,3,2-diazaboroles [(CHNH)2BX, X = H, CN]”. European Journal of Inorganic Chemistry 2015.31 (2015): 5196-5201.