Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs

Xu W-R, Xia G-J, Chow H-F, Cao X-P, Kuck D (2015)
Chemistry - A European Journal 21(34): 12011-12017.

Journal Article | Published | English

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Abstract
A pair of enantiomerically pure metallosquares based on linear platinum-diacetylene edges and tribenzotriquinacene corner units was synthesized. Their structures were characterized by H-1-, C-13- and (PNMR)-P-31 spectroscopy as well as MALDI-TOF mass spectrometry and circular dichroism. Based on DFT calculation, the optimized geometry possesses a distorted square conformation in which the four edges are not sitting on the same plane. The molecular square further self-assembled in the solid state to afford microspheres with diameter of approximately 300nm, as determined by scanning electron microscopy.
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Xu W-R, Xia G-J, Chow H-F, Cao X-P, Kuck D. Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs. Chemistry - A European Journal. 2015;21(34):12011-12017.
Xu, W. - R., Xia, G. - J., Chow, H. - F., Cao, X. - P., & Kuck, D. (2015). Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs. Chemistry - A European Journal, 21(34), 12011-12017.
Xu, W. - R., Xia, G. - J., Chow, H. - F., Cao, X. - P., and Kuck, D. (2015). Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs. Chemistry - A European Journal 21, 12011-12017.
Xu, W.-R., et al., 2015. Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs. Chemistry - A European Journal, 21(34), p 12011-12017.
W.-R. Xu, et al., “Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs”, Chemistry - A European Journal, vol. 21, 2015, pp. 12011-12017.
Xu, W.-R., Xia, G.-J., Chow, H.-F., Cao, X.-P., Kuck, D.: Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs. Chemistry - A European Journal. 21, 12011-12017 (2015).
Xu, Wen-Rong, Xia, Guang-Jie, Chow, Hak-Fun, Cao, Xiao-Ping, and Kuck, Dietmar. “Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs”. Chemistry - A European Journal 21.34 (2015): 12011-12017.
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PMID: 26126897
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