Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex

Oldengott J, Stammler A, Bögge H, Glaser T (2015)
Dalton trans 44(21): 9732-9735.

Journal Article | Published | English

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Abstract
The triplesalophen complex [(baron(Me))Co-3(II)] has been synthesized and characterized. The low-spin Co-II ions possess an (2)A(2) ground state with the magnetic orbitals of d(yz) type. These are well oriented for a strong pi overlap with the bridging phloroglucinol, which results in the strongest ferromagnetic interactions by the spin-polarization mechanism for a 3d phloroglucinol complex.
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Oldengott J, Stammler A, Bögge H, Glaser T. Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex. Dalton trans. 2015;44(21):9732-9735.
Oldengott, J., Stammler, A., Bögge, H., & Glaser, T. (2015). Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex. Dalton trans, 44(21), 9732-9735.
Oldengott, J., Stammler, A., Bögge, H., and Glaser, T. (2015). Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex. Dalton trans 44, 9732-9735.
Oldengott, J., et al., 2015. Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex. Dalton trans, 44(21), p 9732-9735.
J. Oldengott, et al., “Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex”, Dalton trans, vol. 44, 2015, pp. 9732-9735.
Oldengott, J., Stammler, A., Bögge, H., Glaser, T.: Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex. Dalton trans. 44, 9732-9735 (2015).
Oldengott, J, Stammler, Anja, Bögge, Hartmut, and Glaser, Thorsten. “Enhancing the Ferromagnetic Coupling in Extended Phloroglucinol Complexes by Increasing the Metal SOMO - Ligand Overlap: Synthesis and Characterization of a Trinuclear CoII3 Triplesalophen Complex”. Dalton trans 44.21 (2015): 9732-9735.
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PMID: 25946982
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