Synthesis of Chlorosilicates

Steinhauer S, Boettcher T, Schwarze N, Neumann B, Stammler H-G, Hoge B (2014)
Angewandte Chemie International Edition 53(48): 13269-13272.

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Abstract
Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.
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Steinhauer S, Boettcher T, Schwarze N, Neumann B, Stammler H-G, Hoge B. Synthesis of Chlorosilicates. Angewandte Chemie International Edition. 2014;53(48):13269-13272.
Steinhauer, S., Boettcher, T., Schwarze, N., Neumann, B., Stammler, H. - G., & Hoge, B. (2014). Synthesis of Chlorosilicates. Angewandte Chemie International Edition, 53(48), 13269-13272. doi:10.1002/anie.201406311
Steinhauer, S., Boettcher, T., Schwarze, N., Neumann, B., Stammler, H. - G., and Hoge, B. (2014). Synthesis of Chlorosilicates. Angewandte Chemie International Edition 53, 13269-13272.
Steinhauer, S., et al., 2014. Synthesis of Chlorosilicates. Angewandte Chemie International Edition, 53(48), p 13269-13272.
S. Steinhauer, et al., “Synthesis of Chlorosilicates”, Angewandte Chemie International Edition, vol. 53, 2014, pp. 13269-13272.
Steinhauer, S., Boettcher, T., Schwarze, N., Neumann, B., Stammler, H.-G., Hoge, B.: Synthesis of Chlorosilicates. Angewandte Chemie International Edition. 53, 13269-13272 (2014).
Steinhauer, Simon, Boettcher, Tobias, Schwarze, Nico, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Synthesis of Chlorosilicates”. Angewandte Chemie International Edition 53.48 (2014): 13269-13272.
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Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid.
Maskey R, Schädler M, Legler C, Greb L., Angew Chem Int Ed Engl 57(6), 2018
PMID: 29240282
Synthesis of Functional Bis(pentafluoroethyl)silanes (C2 F5 )2 SiX2 , with X=H, F, Cl, Br, OPh, and O2 CCF3.
Schwarze N, Kurscheid B, Steinhauer S, Neumann B, Stammler HG, Ignat'ev N, Hoge B., Chemistry 22(48), 2016
PMID: 27778393
Pentafluoroethylsilicic Acids.
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(50), 2016
PMID: 27862761
Nucleophilic Transfer Reactions of the [Si(C2 F5 )3 ]- Moiety.
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(52), 2016
PMID: 27902862
The Tris(pentafluoroethyl)silanide Anion.
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(52), 2016
PMID: 27902868
A Neutral Silicon/Phosphorus Frustrated Lewis Pair.
Waerder B, Pieper M, Körte LA, Kinder TA, Mix A, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 54(45), 2015
PMID: 26423202

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