Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium

Waerder B, Steinhauer S, Neumann B, Stammler H-G, Mix A, Vishnevskiy Y, Hoge B, Mitzel NW (2014)
Angewandte Chemie International Edition 53(43): 11640-11644.

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Abstract
Lithium carbenoids are versatile compounds for synthesis owing to their intriguing ambiphilic behavior. Although this class of compounds has been known for several years, few solid-state structures exist because of their high reactivity and often low thermal stability. Using cryo X-ray techniques, we were now able to elucidate the first solid-state structure of a Li/F alkyl carbenoid, pentafluoroethyllithium (LiC2F5), finally yielding a prototype for investigating structurereactivity relationships for this class of molecules. The compound forms a diethyl ether-solvated dimer bridged by a rare C-F-Li link. Complementary NMR spectroscopy studies in solution show dynamic processes and indicate rapid exchange of starting material and product. Theoretical investigations help to understand the formation of the observed unusual structural motif.
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Waerder B, Steinhauer S, Neumann B, et al. Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium. Angewandte Chemie International Edition. 2014;53(43):11640-11644.
Waerder, B., Steinhauer, S., Neumann, B., Stammler, H. - G., Mix, A., Vishnevskiy, Y., Hoge, B., et al. (2014). Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium. Angewandte Chemie International Edition, 53(43), 11640-11644.
Waerder, B., Steinhauer, S., Neumann, B., Stammler, H. - G., Mix, A., Vishnevskiy, Y., Hoge, B., and Mitzel, N. W. (2014). Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium. Angewandte Chemie International Edition 53, 11640-11644.
Waerder, B., et al., 2014. Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium. Angewandte Chemie International Edition, 53(43), p 11640-11644.
B. Waerder, et al., “Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium”, Angewandte Chemie International Edition, vol. 53, 2014, pp. 11640-11644.
Waerder, B., Steinhauer, S., Neumann, B., Stammler, H.-G., Mix, A., Vishnevskiy, Y., Hoge, B., Mitzel, N.W.: Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium. Angewandte Chemie International Edition. 53, 11640-11644 (2014).
Waerder, Benedikt, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, Mix, Andreas, Vishnevskiy, Yury, Hoge, Berthold, and Mitzel, Norbert W. “Solid-State Structure of a Li/F Carbenoid: Pentafluoroethyllithium”. Angewandte Chemie International Edition 53.43 (2014): 11640-11644.
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PMID: 25205058
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