Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale

Müller A, Gouzerh P (2014)
Chemistry - A European Journal 20(17): 4862-4873.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
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Abstract / Bemerkung
Spherical porous capsules offer new exciting approaches in chemistry, materials sciences, and in context of physical and biological phenomena. The underlying concepts are reported with particular emphasis on metal oxide based capsules of the {M-132} Keplerate type which displaydue to their exceptional structural features and easy variation/derivatization as well as exchange of building unitsan unmatched range of properties and offer unique opportunities for investigating a variety of basic aspects of nanoscience, including the discovery of some new phenomena, especially those related to hydrophobicity issues that are of significance for everyday life. This relies in particular on the existence of a large number of flexible crown ether type pores/channels and the possibility of changing the interior from completely hydrophilic to completely hydrophobic due to the presence of numerous easily exchangeable internal ligands/functionalities; the capsules can even be constructed so that they enclose a large number of highly active Lewis and BrOnsted acid sites. The manifold of possible applications/uses are outlined as subtitles with reference to results as well as possible future studies. There are, among many others, options to control passing cations under different internal frames allowing also their separations, to conduct studies about hydrophobic recognitions and clustering of biological interest in water, controlled internal ion transport, nanoscale dewetting, and to carry out basic as well as new types of reactions under confined conditions.
Erscheinungsjahr
Zeitschriftentitel
Chemistry - A European Journal
Band
20
Zeitschriftennummer
17
Seite
4862-4873
ISSN
PUB-ID

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Müller A, Gouzerh P. Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale. Chemistry - A European Journal. 2014;20(17):4862-4873.
Müller, A., & Gouzerh, P. (2014). Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale. Chemistry - A European Journal, 20(17), 4862-4873. doi:10.1002/chem.201305010
Müller, A., and Gouzerh, P. (2014). Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale. Chemistry - A European Journal 20, 4862-4873.
Müller, A., & Gouzerh, P., 2014. Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale. Chemistry - A European Journal, 20(17), p 4862-4873.
A. Müller and P. Gouzerh, “Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale”, Chemistry - A European Journal, vol. 20, 2014, pp. 4862-4873.
Müller, A., Gouzerh, P.: Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale. Chemistry - A European Journal. 20, 4862-4873 (2014).
Müller, Achim, and Gouzerh, Pierre. “Capsules with Highly Active Pores and Interiors: Versatile Platforms at the Nanoscale”. Chemistry - A European Journal 20.17 (2014): 4862-4873.

9 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Anionic Hosts for the Incorporation of Cationic Guests.
Peresypkina E, Heindl C, Virovets A, Brake H, Mädl E, Scheer M., Chemistry 24(10), 2018
PMID: 29236336
Small-Molecule Anion Recognition by a Shape-Responsive Bowl-Type Dodecavanadate.
Kuwajima S, Kikukawa Y, Hayashi Y., Chem Asian J 12(15), 2017
PMID: 28432764
The Uptake and Assembly of Alkanes within a Porous Nanocapsule in Water: New Information about Hydrophobic Confinement.
Kopilevich S, Gottlieb H, Keinan-Adamsky K, Müller A, Weinstock IA., Angew Chem Int Ed Engl 55(14), 2016
PMID: 26880403
Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo132 } Capsule System.
Garai S, Bögge H, Merca A, Petina OA, Grego A, Gouzerh P, Haupt ET, Weinstock IA, Müller A., Angew Chem Int Ed Engl 55(23), 2016
PMID: 27140207
Encapsulation of Arenes within a Porous Molybdenum Oxide {Mo132 } Nanocapsule.
Sarma BB, Avram L, Neumann R., Chemistry 22(43), 2016
PMID: 27576915
Molecular containers in complex chemical systems.
Zarra S, Wood DM, Roberts DA, Nitschke JR., Chem Soc Rev 44(2), 2015
PMID: 25029235
A unique fluoride nanocontainer: porous molecular capsules can accommodate an unusually high number of "rather labile" fluoride anions.
Garai S, Rubčić M, Bögge H, Haupt ET, Gouzerh P, Müller A., Angew Chem Int Ed Engl 54(20), 2015
PMID: 25809440

198 References

Daten bereitgestellt von Europe PubMed Central.

Ligand substitution reactions at inorganic centers.
Richens DT., Chem. Rev. 105(6), 2005
PMID: 15941207
Inorganic and bioinorganic solvent exchange mechanisms.
Helm L, Merbach AE., Chem. Rev. 105(6), 2005
PMID: 15941206

Shannon, Acta Crystallogr. Sect. A 32(), 1976

Merca, Chem. Commun. (), 2008

AUTHOR UNKNOWN, 0
Countercation transport modeled by porous spherical molybdenum oxide based nanocapsules.
Rehder D, Haupt ET, Bogge H, Muller A., Chem Asian J 1(1-2), 2006
PMID: 17441040

Rehder, Magn. Reson. Chem. 46(), 2008
Catalysis in a porous molecular capsule: activation by regulated access to sixty metal centers spanning a truncated icosahedron.
Kopilevich S, Gil A, Garcia-Rates M, Bonet-Avalos J, Bo C, Muller A, Weinstock IA., J. Am. Chem. Soc. 134(31), 2012
PMID: 22765884

Steed, 2007

AUTHOR UNKNOWN, 0

Cooper, Angew. Chem. 123(), 2011

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 50(), 2011

Gradoff, Am. J. Bioinform. Res. 2(), 2012
Electrostatically gated membrane permeability in inorganic protocells.
Li M, Harbron RL, Weaver JV, Binks BP, Mann S., Nat Chem 5(6), 2013
PMID: 23695636

AUTHOR UNKNOWN, 0

Gilles, Isr. J. Chem. 53(), 2013
Synthetic ion channels via self-assembly: a route for embedding porous polyoxometalate nanocapsules in lipid bilayer membranes.
Carr R, Weinstock IA, Sivaprasadarao A, Muller A, Aksimentiev A., Nano Lett. 8(11), 2008
PMID: 18844424

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

Atkins, 2002

AUTHOR UNKNOWN, 0

Todea, Chem. Eur. J. 17(), 2011

Todea, Inorg. Chim. Acta. 389(), 2012

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