Sodium Phosphaethynolate as a Building Block for Heterocycles

Chen X, Alidori S, Puschmann FF, Santiso-Quinones G, Benko Z, Li Z, Becker G, Grützmacher H-F, Gruetzmacher H (2014)
Angewandte Chemie International Edition 53(6): 1641-1645.

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Abstract
Phosphorus-containing heterocycles have evolved from laboratory curiosities to functional components, such as ligands in catalytically active metal complexes or molecular constituents in electronic devices. The straightforward synthesis of functionalized heterocycles on a larger scale remains a challenge. Herein, we report the use of the phosphaethynolate (OCP)(-) anion as a building block for various sterically unprotected and functionalized hydroxy substituted phosphorus heterocycles. Because the resulting heterocycles are themselves anions, they are building blocks in their own right and allow further facile functionalization. This property may be of interest in coordination chemistry and material science.
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Chen X, Alidori S, Puschmann FF, et al. Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition. 2014;53(6):1641-1645.
Chen, X., Alidori, S., Puschmann, F. F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., et al. (2014). Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition, 53(6), 1641-1645.
Chen, X., Alidori, S., Puschmann, F. F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., Grützmacher, H. - F., and Gruetzmacher, H. (2014). Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition 53, 1641-1645.
Chen, X., et al., 2014. Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition, 53(6), p 1641-1645.
X. Chen, et al., “Sodium Phosphaethynolate as a Building Block for Heterocycles”, Angewandte Chemie International Edition, vol. 53, 2014, pp. 1641-1645.
Chen, X., Alidori, S., Puschmann, F.F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., Grützmacher, H.-F., Gruetzmacher, H.: Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition. 53, 1641-1645 (2014).
Chen, Xiaodan, Alidori, Simone, Puschmann, Florian Frank, Santiso-Quinones, Gustavo, Benko, Zoltan, Li, Zhongshu, Becker, Gerd, Grützmacher, Hans-Friedrich, and Gruetzmacher, Hansjoerg. “Sodium Phosphaethynolate as a Building Block for Heterocycles”. Angewandte Chemie International Edition 53.6 (2014): 1641-1645.
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2 Citations in Europe PMC

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Synthesis of phosphabenzenes by an iron-catalyzed [2+2+2] cycloaddition reaction of diynes with phosphaalkynes.
Nakajima K, Takata S, Sakata K, Nishibayashi Y., Angew. Chem. Int. Ed. Engl. 54(26), 2015
PMID: 25981197
Phosphaketenes as building blocks for the synthesis of triphospha heterocycles.
Heift D, Benko Z, Grutzmacher H., Chemistry 20(36), 2014
PMID: 25055973

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