Sodium Phosphaethynolate as a Building Block for Heterocycles

Chen X, Alidori S, Puschmann FF, Santiso-Quinones G, Benko Z, Li Z, Becker G, Grützmacher H-F, Gruetzmacher H (2014)
Angewandte Chemie International Edition 53(6): 1641-1645.

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Abstract
Phosphorus-containing heterocycles have evolved from laboratory curiosities to functional components, such as ligands in catalytically active metal complexes or molecular constituents in electronic devices. The straightforward synthesis of functionalized heterocycles on a larger scale remains a challenge. Herein, we report the use of the phosphaethynolate (OCP)(-) anion as a building block for various sterically unprotected and functionalized hydroxy substituted phosphorus heterocycles. Because the resulting heterocycles are themselves anions, they are building blocks in their own right and allow further facile functionalization. This property may be of interest in coordination chemistry and material science.
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Chen X, Alidori S, Puschmann FF, et al. Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition. 2014;53(6):1641-1645.
Chen, X., Alidori, S., Puschmann, F. F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., et al. (2014). Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition, 53(6), 1641-1645. doi:10.1002/anie.201308220
Chen, X., Alidori, S., Puschmann, F. F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., Grützmacher, H. - F., and Gruetzmacher, H. (2014). Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition 53, 1641-1645.
Chen, X., et al., 2014. Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition, 53(6), p 1641-1645.
X. Chen, et al., “Sodium Phosphaethynolate as a Building Block for Heterocycles”, Angewandte Chemie International Edition, vol. 53, 2014, pp. 1641-1645.
Chen, X., Alidori, S., Puschmann, F.F., Santiso-Quinones, G., Benko, Z., Li, Z., Becker, G., Grützmacher, H.-F., Gruetzmacher, H.: Sodium Phosphaethynolate as a Building Block for Heterocycles. Angewandte Chemie International Edition. 53, 1641-1645 (2014).
Chen, Xiaodan, Alidori, Simone, Puschmann, Florian Frank, Santiso-Quinones, Gustavo, Benko, Zoltan, Li, Zhongshu, Becker, Gerd, Grützmacher, Hans-Friedrich, and Gruetzmacher, Hansjoerg. “Sodium Phosphaethynolate as a Building Block for Heterocycles”. Angewandte Chemie International Edition 53.6 (2014): 1641-1645.
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