An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer

Casson I, Muryn CA, Tuna F, Schnack J, Winpenny REP (2013)
Polyhedron 64: 59-62.

Journal Article | Published | English

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Abstract
The synthesis, structure and magnetic properties of an octametallic iron(III) ring is reported. Alternate edges of the ring are bridged by a hydroxide and two pivalates, or by one pivalate and two phenoxides. By addition of biphenol to the reaction a hexadecametallic iron(III) cage can be made where the 16 metals are arranged in two linked {Fe-8} rings. The rings are staggered with respect to one another, and lie on the vertices of an octagonal anti-prism. Magnetic studies on the octametallic ring allows exchange parameters to be obtained. Similar studies on the {Fe-16} barrel shows the exchange interactions within the rings to be similar, with a significant paramagnetic impurity present. (C) 2013 Elsevier Ltd. All rights reserved.
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Casson I, Muryn CA, Tuna F, Schnack J, Winpenny REP. An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer. Polyhedron. 2013;64:59-62.
Casson, I., Muryn, C. A., Tuna, F., Schnack, J., & Winpenny, R. E. P. (2013). An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer. Polyhedron, 64, 59-62.
Casson, I., Muryn, C. A., Tuna, F., Schnack, J., and Winpenny, R. E. P. (2013). An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer. Polyhedron 64, 59-62.
Casson, I., et al., 2013. An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer. Polyhedron, 64, p 59-62.
I. Casson, et al., “An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer”, Polyhedron, vol. 64, 2013, pp. 59-62.
Casson, I., Muryn, C.A., Tuna, F., Schnack, J., Winpenny, R.E.P.: An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer. Polyhedron. 64, 59-62 (2013).
Casson, Ian, Muryn, Christopher A., Tuna, Floriana, Schnack, Jürgen, and Winpenny, Richard E. P. “An {Fe-16} barrel: Synthesis, structural and magnetic characterisation of an {Fe-8} ring and its dimer”. Polyhedron 64 (2013): 59-62.
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