Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer

Sedlovets DM, Shuvalov MV, Vishnevskiy Y, Volkov VT, Khodos II, Trofimov OV, Korepanov VI (2013)
Materials Research Bulletin 48(10): 3955-3960.

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Abstract
Copper polyphthalocyanine (CuPPC), a 2D conjugated polymer, is a promising material for electronics and photovoltaics, but its applications were hindered by a poor processability. We propose an experimental approach, by which thin films of CuPPC, can be directly synthesized in a chemical vapor deposition (CVD) set-up at mild temperature (420 degrees C). High polymerization degree and high crystallinity of the films were confirmed by TEM, FTIR and UV-vis studies. From XRD and TEM electron diffraction, we conclude that the polymer has AA layer stacking with the inter-layer distance of 0.32 nm. The assignment of X-ray and TEM diffraction patterns was based on quantum-chemical calculations. Based on the latter, we also discuss electronic structure and conclude that CuPPC is rather a semi-metal than semi-conductor. (c) 2013 Elsevier Ltd. All rights reserved.
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Sedlovets DM, Shuvalov MV, Vishnevskiy Y, et al. Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer. Materials Research Bulletin. 2013;48(10):3955-3960.
Sedlovets, D. M., Shuvalov, M. V., Vishnevskiy, Y., Volkov, V. T., Khodos, I. I., Trofimov, O. V., & Korepanov, V. I. (2013). Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer. Materials Research Bulletin, 48(10), 3955-3960.
Sedlovets, D. M., Shuvalov, M. V., Vishnevskiy, Y., Volkov, V. T., Khodos, I. I., Trofimov, O. V., and Korepanov, V. I. (2013). Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer. Materials Research Bulletin 48, 3955-3960.
Sedlovets, D.M., et al., 2013. Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer. Materials Research Bulletin, 48(10), p 3955-3960.
D.M. Sedlovets, et al., “Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer”, Materials Research Bulletin, vol. 48, 2013, pp. 3955-3960.
Sedlovets, D.M., Shuvalov, M.V., Vishnevskiy, Y., Volkov, V.T., Khodos, I.I., Trofimov, O.V., Korepanov, V.I.: Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer. Materials Research Bulletin. 48, 3955-3960 (2013).
Sedlovets, Darya M., Shuvalov, Maksim V., Vishnevskiy, Yury, Volkov, Vladimir T., Khodos, Igor I., Trofimov, Oleg V., and Korepanov, Vitaly I. “Synthesis and structure of high-quality films of copper polyphthalocyanine-2D conductive polymer”. Materials Research Bulletin 48.10 (2013): 3955-3960.
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