Experimental and modeling study of the oxidation of n- and iso-butanal

Veloo PS, Dagaut P, Togbé C, Dayma G, Sarathy SM, Westbrook CK, Egolfopoulos FN (2013)
Combustion And Flame 160(9): 1609-1626.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Understanding the kinetics of large molecular weight aldehydes is essential in the context of both conventional and alternative fuels. For example, they are key intermediates formed during the low-temperature oxidation of hydrocarbons as well as during the high-temperature oxidation of oxygenated fuels such as alcohols. In this study, an experimental and kinetic modeling investigation of n-butanal (n-butyraldehyde) and iso-butanal (iso-butyraldehyde or 2-methylpropanal) oxidation kinetics was performed. Experiments were performed in a jet stirred reactor and in counterflow flames over a wide range of equivalence ratios, temperatures, and pressures. The jet stirred reactor was utilized to observe the evolution of stable intermediates and products for the oxidation of n- and iso-butanal at elevated pressures and low to intermediate temperatures. The counterflow configuration was utilized for the determination of laminar flame speeds. A detailed chemical kinetic interpretative model was developed and validated consisting of 244 species and 1198 reactions derived from a previous study of the oxidation of propanal (propionaldehyde). Extensive reaction pathway and sensitivity analysis was performed to provide detailed insight into the mechanisms governing low-, intermediate-, and high-temperature reactivity. The simulation results using the present model are in good agreement with the experimental laminar flame speeds and well within a factor of two of the speciation data obtained in the jet stirred reactor. (c) 2013 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
Erscheinungsjahr
Zeitschriftentitel
Combustion And Flame
Band
160
Zeitschriftennummer
9
Seite
1609-1626
ISSN
PUB-ID

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Veloo PS, Dagaut P, Togbé C, et al. Experimental and modeling study of the oxidation of n- and iso-butanal. Combustion And Flame. 2013;160(9):1609-1626.
Veloo, P. S., Dagaut, P., Togbé, C., Dayma, G., Sarathy, S. M., Westbrook, C. K., & Egolfopoulos, F. N. (2013). Experimental and modeling study of the oxidation of n- and iso-butanal. Combustion And Flame, 160(9), 1609-1626. doi:10.1016/j.combustflame.2013.03.018
Veloo, P. S., Dagaut, P., Togbé, C., Dayma, G., Sarathy, S. M., Westbrook, C. K., and Egolfopoulos, F. N. (2013). Experimental and modeling study of the oxidation of n- and iso-butanal. Combustion And Flame 160, 1609-1626.
Veloo, P.S., et al., 2013. Experimental and modeling study of the oxidation of n- and iso-butanal. Combustion And Flame, 160(9), p 1609-1626.
P.S. Veloo, et al., “Experimental and modeling study of the oxidation of n- and iso-butanal”, Combustion And Flame, vol. 160, 2013, pp. 1609-1626.
Veloo, P.S., Dagaut, P., Togbé, C., Dayma, G., Sarathy, S.M., Westbrook, C.K., Egolfopoulos, F.N.: Experimental and modeling study of the oxidation of n- and iso-butanal. Combustion And Flame. 160, 1609-1626 (2013).
Veloo, Peter S., Dagaut, Philippe, Togbé, Casimir, Dayma, Guillaume, Sarathy, S. Mani, Westbrook, Charles K., and Egolfopoulos, Fokion N. “Experimental and modeling study of the oxidation of n- and iso-butanal”. Combustion And Flame 160.9 (2013): 1609-1626.