A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

Schäffer C, Todea AM, Bögge H, Floquet S, Cadot E, Korenev VS, Fedin VP, Gouzerh P, Müller A (2013)
Dalton Transactions 42(2): 330-333.

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Abstract
Addition of [(Mo2O2)-O-V(mu-O)(mu-S)(aq)](2+) linker-type units to a solution/ dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W-5} units logically in the self-assembly of a mixed oxide/sulphide {(W72Mo60V)-Mo-VI}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (mu-O)(2) and (mu-S)(2) scenarios are known) and providing options to influence differently important capsule-substrate interactions.
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Schäffer C, Todea AM, Bögge H, et al. A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. Dalton Transactions. 2013;42(2):330-333.
Schäffer, C., Todea, A. M., Bögge, H., Floquet, S., Cadot, E., Korenev, V. S., Fedin, V. P., et al. (2013). A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. Dalton Transactions, 42(2), 330-333.
Schäffer, C., Todea, A. M., Bögge, H., Floquet, S., Cadot, E., Korenev, V. S., Fedin, V. P., Gouzerh, P., and Müller, A. (2013). A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. Dalton Transactions 42, 330-333.
Schäffer, C., et al., 2013. A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. Dalton Transactions, 42(2), p 330-333.
C. Schäffer, et al., “A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands”, Dalton Transactions, vol. 42, 2013, pp. 330-333.
Schäffer, C., Todea, A.M., Bögge, H., Floquet, S., Cadot, E., Korenev, V.S., Fedin, V.P., Gouzerh, P., Müller, A.: A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands. Dalton Transactions. 42, 330-333 (2013).
Schäffer, Christian, Todea, Ana Maria, Bögge, Hartmut, Floquet, Sebastien, Cadot, Emmanuel, Korenev, Vladimir S., Fedin, Vladimir P., Gouzerh, Pierre, and Müller, Achim. “A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands”. Dalton Transactions 42.2 (2013): 330-333.
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Tracking "apolar" NMe4+ ions within two polyoxothiomolybdates that have the same pores: smaller clathrate and larger highly porous clusters in action.
Korenev VS, Boulay AG, Haouas M, Bannani F, Fedin VP, Sokolov MN, Terazzi E, Garai S, Muller A, Taulelle F, Marrot J, Leclerc N, Floquet S, Cadot E., Chemistry 20(11), 2014
PMID: 24519761

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