Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties

Berger RJF, Rettenwander D, Spirk S, Wolf C, Patzschke M, Ertl M, Monkowius U, Mitzel NW (2012)
Physical Chemistry Chemical Physics 14(44): 15520-15524.

Journal Article | Published | English

No fulltext has been uploaded

Author
; ; ; ; ; ; ;
Abstract
Relativistic effects in triphenylbismuth have been investigated using a combined experimental and theoretical approach. The influence of these effects on the molecular structure (determined by gas electron diffraction) has been evaluated by means of quantum chemical calculations which consider scalar-relativistic and relativistic effects causing electronic spin-orbit coupling. Besides the molecular structure, different types of spectroscopic techniques (IR, NMR, UV-vis) have been applied and their results have been set in contrast with the results derived from quantum chemical calculations.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Berger RJF, Rettenwander D, Spirk S, et al. Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Physical Chemistry Chemical Physics. 2012;14(44):15520-15524.
Berger, R. J. F., Rettenwander, D., Spirk, S., Wolf, C., Patzschke, M., Ertl, M., Monkowius, U., et al. (2012). Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Physical Chemistry Chemical Physics, 14(44), 15520-15524.
Berger, R. J. F., Rettenwander, D., Spirk, S., Wolf, C., Patzschke, M., Ertl, M., Monkowius, U., and Mitzel, N. W. (2012). Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Physical Chemistry Chemical Physics 14, 15520-15524.
Berger, R.J.F., et al., 2012. Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Physical Chemistry Chemical Physics, 14(44), p 15520-15524.
R.J.F. Berger, et al., “Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties”, Physical Chemistry Chemical Physics, vol. 14, 2012, pp. 15520-15524.
Berger, R.J.F., Rettenwander, D., Spirk, S., Wolf, C., Patzschke, M., Ertl, M., Monkowius, U., Mitzel, N.W.: Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Physical Chemistry Chemical Physics. 14, 15520-15524 (2012).
Berger, Raphael J. F., Rettenwander, Daniel, Spirk, Stefan, Wolf, Christian, Patzschke, Michael, Ertl, Martin, Monkowius, Uwe, and Mitzel, Norbert W. “Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties”. Physical Chemistry Chemical Physics 14.44 (2012): 15520-15524.
This data publication is cited in the following publications:
This publication cites the following data publications:

5 Citations in Europe PMC

Data provided by Europe PubMed Central.

Photoreductive generation of amorphous bismuth nanoparticles using polysaccharides--bismuth-cellulose nanocomposites.
Breitwieser D, Kriechbaum M, Ehmann HM, Monkowius U, Coseri S, Sacarescu L, Spirk S., Carbohydr Polym 116(), 2015
PMID: 25458299
Hemi- and holo-directed lead(II) complexes in a soft ligand environment.
Imran M, Mix A, Neumann B, Stammler HG, Monkowius U, Grundlinger P, Mitzel NW., Dalton Trans 44(3), 2015
PMID: 25104214
Synthesis, structural and photo-physical studies of bismuth(III) complexes with Janus scorpionate and co-ligands.
Imran M, Mix A, Neumann B, Stammler HG, Monkowius U, Bleckenwegner P, Mitzel NW., Dalton Trans 43(28), 2014
PMID: 24906201
Borate-based ligands with two soft heterocycle/thione groups and their sodium and bismuth complexes.
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 43(3), 2014
PMID: 24190102
The versatile behaviour of a novel Janus scorpionate ligand towards sodium, potassium and bismuth(III) ions.
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 42(44), 2013
PMID: 24071804

35 References

Data provided by Europe PubMed Central.


Schreckenbach, J. Phys. Chem. 99(), 1995

Schreckenbach, Int. J. Quantum Chem. 60(), 1996

Schreckenbach, Int. J. Quantum Chem. 61(), 1997

Wolff, J. Chem. Phys. 109(), 1998

Wolff, J. Chem. Phys. 110(), 1999

Pyykkö, J. Chem. Soc., Faraday Trans. 2 75(), 1979

Wann, Dalton Trans. (), 2006

Nomura, Tetrahedron Lett. (), 1969

Hrobárik, J. Chem. Phys. A. 115(), 2011

Kaupp, Chem.–Eur. J. 4(), 1998

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Sources

PMID: 23072773
PubMed | Europe PMC

Search this title in

Google Scholar