Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes

Feldscher B, Theil H, Stammler A, Bögge H, Glaser T (2012)
Inorganic Chemistry 51(16): 8652-8654.

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Abstract
An unprecedented trinucleating ligand with a central 1,3,5-trimercaptobenzene unit and its trinuclear Cu-3(II) complex are presented. The high covalency of the difficult-to-realize Cu-II-SR bond provides an order of magnitude increase in the superexchange interaction in comparison to its oxygen analogue.
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Feldscher B, Theil H, Stammler A, Bögge H, Glaser T. Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry. 2012;51(16):8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., & Glaser, T. (2012). Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry, 51(16), 8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., and Glaser, T. (2012). Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry 51, 8652-8654.
Feldscher, B., et al., 2012. Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry, 51(16), p 8652-8654.
B. Feldscher, et al., “Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes”, Inorganic Chemistry, vol. 51, 2012, pp. 8652-8654.
Feldscher, B., Theil, H., Stammler, A., Bögge, H., Glaser, T.: Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry. 51, 8652-8654 (2012).
Feldscher, Bastian, Theil, Hubert, Stammler, Anja, Bögge, Hartmut, and Glaser, Thorsten. “Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes”. Inorganic Chemistry 51.16 (2012): 8652-8654.
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A streamlined synthesis of extended thiophloroglucinol ligands and their trinuclear NiII3 complexes.
Feldscher B, Theil H, Stammler A, Bogge H, Glaser T., Dalton Trans 43(10), 2014
PMID: 24457995

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